Eintrag weiter verarbeiten

Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems

Gespeichert in:

Personen und Körperschaften: Mueller, Steve, Waechtler, Thomas, Hofmann, Lutz, Tuchscherer, Andre, Mothes, Robert, Gordan, Ovidiu, Lehmann, Daniel, Haidu, Francisc, Ogiewa, Marcel, Gerlich, Lukas, Ding, Shao-Feng, Schulz, Stefan E., Gessner, Thomas, Lang, Heinrich, Zahn, Dietrich R.T, Qu, Xin-Ping
Titel: Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems
Format: E-Book
Sprache: Englisch
veröffentlicht:
Piscataway IEEE 2011
Online-Ausg.. 2012
Gesamtaufnahme: Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems; Semiconductor Conference Dresden (SCD), 27-28 Sept. 2011, Dresden, Germany; DOI: 10.1109/SCD.2011.6068736
Schlagwörter:
Ald
Ecd
Quelle: Qucosa
LEADER 03384nam a2200745 c 4500
001 22-ch1-qucosa-84003
007 cr
008 2011 eng
037 |a urn:nbn:de:bsz:ch1-qucosa-84003 
041 |a eng 
082 |a 600 
100 |a Mueller, Steve 
245 |a Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems 
264 |a Piscataway  |b IEEE  |c 2011 
336 |b txt 
338 |b nc 
533 |a Online-Ausg.  |d 2012  |e Online-Ressource (Text)  |f Universitätsbibliothek Chemnitz 
520 |a In this work, an approach for copper atomic layer deposition (ALD) via reduction of CuxO films was investigated regarding applications in ULSI interconnects, like Cu seed layers directly grown on diffusion barriers (e. g. TaN) or possible liner materials (e. g. Ru or Ni) as well as non-ferromagnetic spacer layers between ferromagnetic films in GMR sensor elements, like Ni or Co. The thermal CuxO ALD process is based on the Cu (I) β-diketonate precursor [(nBu3P)2Cu(acac)] and a mixture of water vapor and oxygen ("wet O2") as co-reactant at temperatures between 100 and 130 °C. Highly efficient conversions of the CuxO to metallic Cu films are realized by a vapor phase treatment with formic acid (HCOOH), especially on Ru substrates. Electrochemical deposition (ECD) experiments on Cu ALD seed / Ru liner stacks in typical interconnect patterns are showing nearly perfectly filling behavior. For improving the HCOOH reduction on arbitrary substrates, a catalytic amount of Ru was successful introduced into the CuxO films during the ALD with a precursor mixture of the Cu (I) β-diketonate and an organometallic Ru precursor. Furthermore, molecular and atomic hydrogen were studied as promising alternative reducing agents. 
650 |a Atomlagenabscheidung 
650 |a Ald 
650 |a Ruthenium 
650 |a Ameisensäure 
650 |a Wasserstoff 
650 |a Reduktion 
650 |a Ulsi 
650 |a Metallisierung 
650 |a Galvanik 
650 |a Spintronik 
650 |a Atomic Layer Deposition 
650 |a Ald 
650 |a Copper Oxide 
650 |a Ruthenium 
650 |a Formic Acid 
650 |a Hydrogen 
650 |a Reduction 
650 |a Ulsi 
650 |a Interconnect 
650 |a Electrochemical Deposition 
650 |a Ecd 
650 |a Spintronics 
650 |a Atomlagenabscheidung 
650 |a Kupferoxid 
650 |a Ruthenium 
650 |a Metallisieren 
650 |a Galvanische Beschichtung 
650 |a Kupfer 
655 |a Konferenzschrift 
700 |a Waechtler, Thomas 
700 |a Hofmann, Lutz 
700 |a Tuchscherer, Andre 
700 |a Mothes, Robert 
700 |a Gordan, Ovidiu 
700 |a Lehmann, Daniel 
700 |a Haidu, Francisc 
700 |a Ogiewa, Marcel 
700 |a Gerlich, Lukas 
700 |a Ding, Shao-Feng 
700 |a Schulz, Stefan E. 
700 |a Gessner, Thomas 
700 |a Lang, Heinrich 
700 |a Zahn, Dietrich R.T. 
700 |a Qu, Xin-Ping 
773 |g Semiconductor Conference Dresden (SCD), 27-28 Sept. 2011, Dresden, Germany; DOI: 10.1109/SCD.2011.6068736 
856 4 0 |q text/html  |u https://nbn-resolving.org/urn:nbn:de:bsz:ch1-qucosa-84003  |z Online-Zugriff 
980 |a ch1-qucosa-84003  |b 22  |c sid-22-col-qucosa 
openURL url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=Thermal+ALD+of+Cu+via+Reduction+of+CuxO+films+for+the+Advanced+Metallization+in+Spintronic+and+ULSI+Interconnect+Systems&rft.date=2011&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Adc&rft.creator=Mueller%2C+Steve&rft.pub=IEEE&rft.format=eBook&rft.language=English
SOLR
_version_ 1797636852380860416
author Mueller, Steve
author2 Waechtler, Thomas, Hofmann, Lutz, Tuchscherer, Andre, Mothes, Robert, Gordan, Ovidiu, Lehmann, Daniel, Haidu, Francisc, Ogiewa, Marcel, Gerlich, Lukas, Ding, Shao-Feng, Schulz, Stefan E., Gessner, Thomas, Lang, Heinrich, Zahn, Dietrich R.T, Qu, Xin-Ping
author2_role , , , , , , , , , , , , , ,
author2_variant t w tw, l h lh, a t at, r m rm, o g og, d l dl, f h fh, m o mo, l g lg, s f d sfd, s e s se ses, t g tg, h l hl, d r z dr drz, x p q xpq
author_facet Mueller, Steve, Waechtler, Thomas, Hofmann, Lutz, Tuchscherer, Andre, Mothes, Robert, Gordan, Ovidiu, Lehmann, Daniel, Haidu, Francisc, Ogiewa, Marcel, Gerlich, Lukas, Ding, Shao-Feng, Schulz, Stefan E., Gessner, Thomas, Lang, Heinrich, Zahn, Dietrich R.T, Qu, Xin-Ping
author_role
author_sort Mueller, Steve
author_variant s m sm
building Library A
collection sid-22-col-qucosa
container_reference Semiconductor Conference Dresden (SCD), 27-28 Sept. 2011, Dresden, Germany; DOI: 10.1109/SCD.2011.6068736
contents In this work, an approach for copper atomic layer deposition (ALD) via reduction of CuxO films was investigated regarding applications in ULSI interconnects, like Cu seed layers directly grown on diffusion barriers (e. g. TaN) or possible liner materials (e. g. Ru or Ni) as well as non-ferromagnetic spacer layers between ferromagnetic films in GMR sensor elements, like Ni or Co. The thermal CuxO ALD process is based on the Cu (I) β-diketonate precursor [(nBu3P)2Cu(acac)] and a mixture of water vapor and oxygen ("wet O2") as co-reactant at temperatures between 100 and 130 °C. Highly efficient conversions of the CuxO to metallic Cu films are realized by a vapor phase treatment with formic acid (HCOOH), especially on Ru substrates. Electrochemical deposition (ECD) experiments on Cu ALD seed / Ru liner stacks in typical interconnect patterns are showing nearly perfectly filling behavior. For improving the HCOOH reduction on arbitrary substrates, a catalytic amount of Ru was successful introduced into the CuxO films during the ALD with a precursor mixture of the Cu (I) β-diketonate and an organometallic Ru precursor. Furthermore, molecular and atomic hydrogen were studied as promising alternative reducing agents.
dewey-full 600
dewey-hundreds 600 - Technology (Applied sciences)
dewey-ones 600 - Technology (Applied sciences)
dewey-raw 600
dewey-search 600
dewey-sort 3600
dewey-tens 600 - Technology (Applied sciences)
facet_avail Online, Free
finc_class_facet Technik
fincclass_txtF_mv technology
format eBook
format_access_txtF_mv Book, E-Book
format_de105 Ebook
format_de14 Book, E-Book
format_de15 Book, E-Book
format_del152 Buch
format_detail_txtF_mv text-online-monograph-independent-conference
format_dezi4 e-Book
format_finc Book, E-Book
format_legacy ElectronicBook
format_legacy_nrw Book, E-Book
format_nrw Book, E-Book
format_strict_txtF_mv E-Book
genre Konferenzschrift
genre_facet Konferenzschrift
geogr_code not assigned
geogr_code_person not assigned
hierarchy_sequence Semiconductor Conference Dresden (SCD), 27-28 Sept. 2011, Dresden, Germany; DOI: 10.1109/SCD.2011.6068736
id 22-ch1-qucosa-84003
illustrated Not Illustrated
imprint Piscataway, IEEE, 2011
imprint_str_mv Online-Ausg.: 2012
institution DE-105, DE-Gla1, DE-Brt1, DE-D161, DE-540, DE-Pl11, DE-Rs1, DE-Bn3, DE-Zi4, DE-Zwi2, DE-D117, DE-Mh31, DE-D275, DE-Ch1, DE-15, DE-D13, DE-L242, DE-L229, DE-L328
is_hierarchy_id
is_hierarchy_title
language English
last_indexed 2024-04-29T03:08:14.837Z
match_str mueller2011thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems
mega_collection Qucosa
publishDate 2011
publishDateSort 2011
publishPlace Piscataway
publisher IEEE
record_format marcfinc
record_id ch1-qucosa-84003
recordtype marcfinc
rvk_facet No subject assigned
source_id 22
spelling Mueller, Steve, Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems, Piscataway IEEE 2011, txt, nc, Online-Ausg. 2012 Online-Ressource (Text) Universitätsbibliothek Chemnitz, In this work, an approach for copper atomic layer deposition (ALD) via reduction of CuxO films was investigated regarding applications in ULSI interconnects, like Cu seed layers directly grown on diffusion barriers (e. g. TaN) or possible liner materials (e. g. Ru or Ni) as well as non-ferromagnetic spacer layers between ferromagnetic films in GMR sensor elements, like Ni or Co. The thermal CuxO ALD process is based on the Cu (I) β-diketonate precursor [(nBu3P)2Cu(acac)] and a mixture of water vapor and oxygen ("wet O2") as co-reactant at temperatures between 100 and 130 °C. Highly efficient conversions of the CuxO to metallic Cu films are realized by a vapor phase treatment with formic acid (HCOOH), especially on Ru substrates. Electrochemical deposition (ECD) experiments on Cu ALD seed / Ru liner stacks in typical interconnect patterns are showing nearly perfectly filling behavior. For improving the HCOOH reduction on arbitrary substrates, a catalytic amount of Ru was successful introduced into the CuxO films during the ALD with a precursor mixture of the Cu (I) β-diketonate and an organometallic Ru precursor. Furthermore, molecular and atomic hydrogen were studied as promising alternative reducing agents., Atomlagenabscheidung, Ald, Ruthenium, Ameisensäure, Wasserstoff, Reduktion, Ulsi, Metallisierung, Galvanik, Spintronik, Atomic Layer Deposition, Copper Oxide, Formic Acid, Hydrogen, Reduction, Interconnect, Electrochemical Deposition, Ecd, Spintronics, Kupferoxid, Metallisieren, Galvanische Beschichtung, Kupfer, Konferenzschrift, Waechtler, Thomas, Hofmann, Lutz, Tuchscherer, Andre, Mothes, Robert, Gordan, Ovidiu, Lehmann, Daniel, Haidu, Francisc, Ogiewa, Marcel, Gerlich, Lukas, Ding, Shao-Feng, Schulz, Stefan E., Gessner, Thomas, Lang, Heinrich, Zahn, Dietrich R.T., Qu, Xin-Ping, Semiconductor Conference Dresden (SCD), 27-28 Sept. 2011, Dresden, Germany; DOI: 10.1109/SCD.2011.6068736, text/html https://nbn-resolving.org/urn:nbn:de:bsz:ch1-qucosa-84003 Online-Zugriff
spellingShingle Mueller, Steve, Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems, In this work, an approach for copper atomic layer deposition (ALD) via reduction of CuxO films was investigated regarding applications in ULSI interconnects, like Cu seed layers directly grown on diffusion barriers (e. g. TaN) or possible liner materials (e. g. Ru or Ni) as well as non-ferromagnetic spacer layers between ferromagnetic films in GMR sensor elements, like Ni or Co. The thermal CuxO ALD process is based on the Cu (I) β-diketonate precursor [(nBu3P)2Cu(acac)] and a mixture of water vapor and oxygen ("wet O2") as co-reactant at temperatures between 100 and 130 °C. Highly efficient conversions of the CuxO to metallic Cu films are realized by a vapor phase treatment with formic acid (HCOOH), especially on Ru substrates. Electrochemical deposition (ECD) experiments on Cu ALD seed / Ru liner stacks in typical interconnect patterns are showing nearly perfectly filling behavior. For improving the HCOOH reduction on arbitrary substrates, a catalytic amount of Ru was successful introduced into the CuxO films during the ALD with a precursor mixture of the Cu (I) β-diketonate and an organometallic Ru precursor. Furthermore, molecular and atomic hydrogen were studied as promising alternative reducing agents., Atomlagenabscheidung, Ald, Ruthenium, Ameisensäure, Wasserstoff, Reduktion, Ulsi, Metallisierung, Galvanik, Spintronik, Atomic Layer Deposition, Copper Oxide, Formic Acid, Hydrogen, Reduction, Interconnect, Electrochemical Deposition, Ecd, Spintronics, Kupferoxid, Metallisieren, Galvanische Beschichtung, Kupfer, Konferenzschrift
title Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems
title_auth Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems
title_full Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems
title_fullStr Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems
title_full_unstemmed Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems
title_in_hierarchy
title_short Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems
title_sort thermal ald of cu via reduction of cuxo films for the advanced metallization in spintronic and ulsi interconnect systems
title_unstemmed Thermal ALD of Cu via Reduction of CuxO films for the Advanced Metallization in Spintronic and ULSI Interconnect Systems
topic Atomlagenabscheidung, Ald, Ruthenium, Ameisensäure, Wasserstoff, Reduktion, Ulsi, Metallisierung, Galvanik, Spintronik, Atomic Layer Deposition, Copper Oxide, Formic Acid, Hydrogen, Reduction, Interconnect, Electrochemical Deposition, Ecd, Spintronics, Kupferoxid, Metallisieren, Galvanische Beschichtung, Kupfer, Konferenzschrift
topic_facet Atomlagenabscheidung, Ald, Ruthenium, Ameisensäure, Wasserstoff, Reduktion, Ulsi, Metallisierung, Galvanik, Spintronik, Atomic Layer Deposition, Copper Oxide, Formic Acid, Hydrogen, Reduction, Interconnect, Electrochemical Deposition, Ecd, Spintronics, Kupferoxid, Metallisieren, Galvanische Beschichtung, Kupfer, Konferenzschrift
url https://nbn-resolving.org/urn:nbn:de:bsz:ch1-qucosa-84003
urn urn:nbn:de:bsz:ch1-qucosa-84003
work_keys_str_mv AT muellersteve thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT waechtlerthomas thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT hofmannlutz thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT tuchschererandre thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT mothesrobert thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT gordanovidiu thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT lehmanndaniel thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT haidufrancisc thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT ogiewamarcel thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT gerlichlukas thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT dingshaofeng thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT schulzstefane thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT gessnerthomas thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT langheinrich thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT zahndietrichrt thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems, AT quxinping thermalaldofcuviareductionofcuxofilmsfortheadvancedmetallizationinspintronicandulsiinterconnectsystems