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Recombination of iodine atoms in sulfur dioxide
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| Zeitschriftentitel: | Canadian Journal of Chemistry |
|---|---|
| Personen und Körperschaften: | , |
| In: | Canadian Journal of Chemistry, 48, 1970, 13, S. 2133-2134 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Canadian Science Publishing
|
| Schlagwörter: |
| author_facet |
Brown, J. Burns, G. Brown, J. Burns, G. |
|---|---|
| author |
Brown, J. Burns, G. |
| spellingShingle |
Brown, J. Burns, G. Canadian Journal of Chemistry Recombination of iodine atoms in sulfur dioxide Organic Chemistry General Chemistry Catalysis |
| author_sort |
brown, j. |
| spelling |
Brown, J. Burns, G. 0008-4042 1480-3291 Canadian Science Publishing Organic Chemistry General Chemistry Catalysis http://dx.doi.org/10.1139/v70-354 <jats:p> The reaction 2I + SO<jats:sub>2</jats:sub> → I<jats:sub>2</jats:sub> + SO<jats:sub>2</jats:sub> has been studied between 293 and 668°K. At 293°K, the recombination rate constant is 2.6 × 10<jats:sup>10</jats:sup>]<jats:sup>2</jats:sup> mole<jats:sup>−2</jats:sup> s<jats:sup>−1</jats:sup>; it attains 1/10 of this value at 668°K. Although the infrared and ultraviolet spectra of SO<jats:sub>2</jats:sub>, studied previously, suggest the existence of two forms of SO<jats:sub>2</jats:sub> in the temperature range in question, the present recombination studies present no further supporting evidence about the existence of the excited form. </jats:p> Recombination of iodine atoms in sulfur dioxide Canadian Journal of Chemistry |
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Canadian Science Publishing, 1970 |
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Canadian Science Publishing, 1970 |
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0008-4042 1480-3291 |
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0008-4042 1480-3291 |
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1970 |
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Canadian Science Publishing |
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Canadian Journal of Chemistry |
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49 |
| title |
Recombination of iodine atoms in sulfur dioxide |
| title_unstemmed |
Recombination of iodine atoms in sulfur dioxide |
| title_full |
Recombination of iodine atoms in sulfur dioxide |
| title_fullStr |
Recombination of iodine atoms in sulfur dioxide |
| title_full_unstemmed |
Recombination of iodine atoms in sulfur dioxide |
| title_short |
Recombination of iodine atoms in sulfur dioxide |
| title_sort |
recombination of iodine atoms in sulfur dioxide |
| topic |
Organic Chemistry General Chemistry Catalysis |
| url |
http://dx.doi.org/10.1139/v70-354 |
| publishDate |
1970 |
| physical |
2133-2134 |
| description |
<jats:p> The reaction 2I + SO<jats:sub>2</jats:sub> → I<jats:sub>2</jats:sub> + SO<jats:sub>2</jats:sub> has been studied between 293 and 668°K. At 293°K, the recombination rate constant is 2.6 × 10<jats:sup>10</jats:sup>]<jats:sup>2</jats:sup> mole<jats:sup>−2</jats:sup> s<jats:sup>−1</jats:sup>; it attains 1/10 of this value at 668°K. Although the infrared and ultraviolet spectra of SO<jats:sub>2</jats:sub>, studied previously, suggest the existence of two forms of SO<jats:sub>2</jats:sub> in the temperature range in question, the present recombination studies present no further supporting evidence about the existence of the excited form. </jats:p> |
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| author | Brown, J., Burns, G. |
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| container_start_page | 2133 |
| container_title | Canadian Journal of Chemistry |
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| description | <jats:p> The reaction 2I + SO<jats:sub>2</jats:sub> → I<jats:sub>2</jats:sub> + SO<jats:sub>2</jats:sub> has been studied between 293 and 668°K. At 293°K, the recombination rate constant is 2.6 × 10<jats:sup>10</jats:sup>]<jats:sup>2</jats:sup> mole<jats:sup>−2</jats:sup> s<jats:sup>−1</jats:sup>; it attains 1/10 of this value at 668°K. Although the infrared and ultraviolet spectra of SO<jats:sub>2</jats:sub>, studied previously, suggest the existence of two forms of SO<jats:sub>2</jats:sub> in the temperature range in question, the present recombination studies present no further supporting evidence about the existence of the excited form. </jats:p> |
| doi_str_mv | 10.1139/v70-354 |
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| imprint | Canadian Science Publishing, 1970 |
| imprint_str_mv | Canadian Science Publishing, 1970 |
| institution | DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Zi4, DE-Gla1, DE-15, DE-Pl11, DE-Rs1, DE-14, DE-105 |
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| physical | 2133-2134 |
| publishDate | 1970 |
| publishDateSort | 1970 |
| publisher | Canadian Science Publishing |
| record_format | ai |
| recordtype | ai |
| series | Canadian Journal of Chemistry |
| source_id | 49 |
| spelling | Brown, J. Burns, G. 0008-4042 1480-3291 Canadian Science Publishing Organic Chemistry General Chemistry Catalysis http://dx.doi.org/10.1139/v70-354 <jats:p> The reaction 2I + SO<jats:sub>2</jats:sub> → I<jats:sub>2</jats:sub> + SO<jats:sub>2</jats:sub> has been studied between 293 and 668°K. At 293°K, the recombination rate constant is 2.6 × 10<jats:sup>10</jats:sup>]<jats:sup>2</jats:sup> mole<jats:sup>−2</jats:sup> s<jats:sup>−1</jats:sup>; it attains 1/10 of this value at 668°K. Although the infrared and ultraviolet spectra of SO<jats:sub>2</jats:sub>, studied previously, suggest the existence of two forms of SO<jats:sub>2</jats:sub> in the temperature range in question, the present recombination studies present no further supporting evidence about the existence of the excited form. </jats:p> Recombination of iodine atoms in sulfur dioxide Canadian Journal of Chemistry |
| spellingShingle | Brown, J., Burns, G., Canadian Journal of Chemistry, Recombination of iodine atoms in sulfur dioxide, Organic Chemistry, General Chemistry, Catalysis |
| title | Recombination of iodine atoms in sulfur dioxide |
| title_full | Recombination of iodine atoms in sulfur dioxide |
| title_fullStr | Recombination of iodine atoms in sulfur dioxide |
| title_full_unstemmed | Recombination of iodine atoms in sulfur dioxide |
| title_short | Recombination of iodine atoms in sulfur dioxide |
| title_sort | recombination of iodine atoms in sulfur dioxide |
| title_unstemmed | Recombination of iodine atoms in sulfur dioxide |
| topic | Organic Chemistry, General Chemistry, Catalysis |
| url | http://dx.doi.org/10.1139/v70-354 |