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Recombination of iodine atoms in sulfur dioxide
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| Zeitschriftentitel: | Canadian Journal of Chemistry |
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| Personen und Körperschaften: | , |
| In: | Canadian Journal of Chemistry, 48, 1970, 13, S. 2133-2134 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Canadian Science Publishing
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| Schlagwörter: |
| Zusammenfassung: | <jats:p> The reaction 2I + SO<jats:sub>2</jats:sub> → I<jats:sub>2</jats:sub> + SO<jats:sub>2</jats:sub> has been studied between 293 and 668°K. At 293°K, the recombination rate constant is 2.6 × 10<jats:sup>10</jats:sup>]<jats:sup>2</jats:sup> mole<jats:sup>−2</jats:sup> s<jats:sup>−1</jats:sup>; it attains 1/10 of this value at 668°K. Although the infrared and ultraviolet spectra of SO<jats:sub>2</jats:sub>, studied previously, suggest the existence of two forms of SO<jats:sub>2</jats:sub> in the temperature range in question, the present recombination studies present no further supporting evidence about the existence of the excited form. </jats:p> |
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| Umfang: | 2133-2134 |
| ISSN: |
0008-4042
1480-3291 |
| DOI: | 10.1139/v70-354 |