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{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]bip...
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| Zeitschriftentitel: | IUCrData |
|---|---|
| Personen und Körperschaften: | , , |
| In: | IUCrData, 1, 2016, 12 |
| Format: | E-Article |
| Sprache: | Unbestimmt |
| veröffentlicht: |
International Union of Crystallography (IUCr)
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| Schlagwörter: |
| author_facet |
Selent, Detlef Spannenberg, Anke Börner, Armin Selent, Detlef Spannenberg, Anke Börner, Armin |
|---|---|
| author |
Selent, Detlef Spannenberg, Anke Börner, Armin |
| spellingShingle |
Selent, Detlef Spannenberg, Anke Börner, Armin IUCrData {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate General Earth and Planetary Sciences General Environmental Science |
| author_sort |
selent, detlef |
| spelling |
Selent, Detlef Spannenberg, Anke Börner, Armin 2414-3146 International Union of Crystallography (IUCr) General Earth and Planetary Sciences General Environmental Science http://dx.doi.org/10.1107/s2414314616019143 <jats:p>The molecule of the title compound, [Rh(C<jats:sub>42</jats:sub>H<jats:sub>62</jats:sub>O<jats:sub>3</jats:sub>P)(C<jats:sub>74</jats:sub>H<jats:sub>68</jats:sub>O<jats:sub>4</jats:sub>P<jats:sub>2</jats:sub>]·2.7C<jats:sub>7</jats:sub>D<jats:sub>8</jats:sub>, consists of two phospharhodacyclic substructures sharing the Rh atom, which are formed by coordination/<jats:italic>ortho</jats:italic>-metallation of a triaryl phosphite, and by the coordination of a rigid bisphosphite, respectively. The metal displays a tetrahedrally distorted square-planar coordination geometry. A<jats:italic>tert</jats:italic>-butyl group shows rotational disorder over two positions with refined site occupancy of 0.561 (3):0.439 (3). Two partial-occupancy toluene solvent molecules are disordered over two orientations with site occupancies of 0.5:0.3 and 0.5:0.4, respectively. Intramolecular C—H...O hydrogen bonds are observed. In the crystal, complex molecules and toluene solvent molecules pack as alternating layers parallel to the<jats:italic>ac</jats:italic>plane.</jats:p> {2-[Bis(2,4-di-<i>tert</i>-butylphenoxy)phosphanyloxy-κ<i>P</i>]-3,5-di-<i>tert</i>-butylphenyl-κ<i>C</i><sup>1</sup>}{3,3′-di-<i>tert</i>-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κ<i>P</i>]biphenyl}rhodium(I) toluene-<i>d</i><sub>8</sub>2.7-solvate IUCrData |
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10.1107/s2414314616019143 |
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Online Free |
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ElectronicArticle |
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blob:ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTEwNy9zMjQxNDMxNDYxNjAxOTE0Mw |
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ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTEwNy9zMjQxNDMxNDYxNjAxOTE0Mw |
| institution |
DE-L229 DE-D275 DE-Bn3 DE-Brt1 DE-Zwi2 DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Rs1 DE-Pl11 DE-105 DE-14 DE-Ch1 |
| imprint |
International Union of Crystallography (IUCr), 2016 |
| imprint_str_mv |
International Union of Crystallography (IUCr), 2016 |
| issn |
2414-3146 |
| issn_str_mv |
2414-3146 |
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Undetermined |
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International Union of Crystallography (IUCr) (CrossRef) |
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selent20162bis24ditertbutylphenoxyphosphanyloxykp35ditertbutylphenylkc133ditertbutyl55dimethoxy22bis1122tetraphenylethane12dioxyphosphanyloxykpbiphenylrhodiumitoluened827solvate |
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2016 |
| publisher |
International Union of Crystallography (IUCr) |
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ai |
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IUCrData |
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49 |
| title |
{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_unstemmed |
{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_full |
{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_fullStr |
{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_full_unstemmed |
{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_short |
{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_sort |
{2-[bis(2,4-di-<i>tert</i>-butylphenoxy)phosphanyloxy-κ<i>p</i>]-3,5-di-<i>tert</i>-butylphenyl-κ<i>c</i><sup>1</sup>}{3,3′-di-<i>tert</i>-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κ<i>p</i>]biphenyl}rhodium(i) toluene-<i>d</i><sub>8</sub>2.7-solvate |
| topic |
General Earth and Planetary Sciences General Environmental Science |
| url |
http://dx.doi.org/10.1107/s2414314616019143 |
| publishDate |
2016 |
| physical |
|
| description |
<jats:p>The molecule of the title compound, [Rh(C<jats:sub>42</jats:sub>H<jats:sub>62</jats:sub>O<jats:sub>3</jats:sub>P)(C<jats:sub>74</jats:sub>H<jats:sub>68</jats:sub>O<jats:sub>4</jats:sub>P<jats:sub>2</jats:sub>]·2.7C<jats:sub>7</jats:sub>D<jats:sub>8</jats:sub>, consists of two phospharhodacyclic substructures sharing the Rh atom, which are formed by coordination/<jats:italic>ortho</jats:italic>-metallation of a triaryl phosphite, and by the coordination of a rigid bisphosphite, respectively. The metal displays a tetrahedrally distorted square-planar coordination geometry. A<jats:italic>tert</jats:italic>-butyl group shows rotational disorder over two positions with refined site occupancy of 0.561 (3):0.439 (3). Two partial-occupancy toluene solvent molecules are disordered over two orientations with site occupancies of 0.5:0.3 and 0.5:0.4, respectively. Intramolecular C—H...O hydrogen bonds are observed. In the crystal, complex molecules and toluene solvent molecules pack as alternating layers parallel to the<jats:italic>ac</jats:italic>plane.</jats:p> |
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url_ver=Z39.88-2004&ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fvufind.svn.sourceforge.net%3Agenerator&rft.title=%7B2-%5BBis%282%2C4-di-tert-butylphenoxy%29phosphanyloxy-%CE%BAP%5D-3%2C5-di-tert-butylphenyl-%CE%BAC1%7D%7B3%2C3%E2%80%B2-di-tert-butyl-5%2C5%E2%80%B2-dimethoxy-2%2C2%E2%80%B2-bis%5B%281%2C1%2C2%2C2-tetraphenylethane-1%2C2-dioxy%29phosphanyloxy-%CE%BAP%5Dbiphenyl%7Drhodium%28I%29+toluene-d82.7-solvate&rft.date=2016-12-28&genre=article&issn=2414-3146&volume=1&issue=12&jtitle=IUCrData&atitle=%7B2-%5BBis%282%2C4-di-%3Ci%3Etert%3C%2Fi%3E-butylphenoxy%29phosphanyloxy-%CE%BA%3Ci%3EP%3C%2Fi%3E%5D-3%2C5-di-%3Ci%3Etert%3C%2Fi%3E-butylphenyl-%CE%BA%3Ci%3EC%3C%2Fi%3E%3Csup%3E1%3C%2Fsup%3E%7D%7B3%2C3%E2%80%B2-di-%3Ci%3Etert%3C%2Fi%3E-butyl-5%2C5%E2%80%B2-dimethoxy-2%2C2%E2%80%B2-bis%5B%281%2C1%2C2%2C2-tetraphenylethane-1%2C2-dioxy%29phosphanyloxy-%CE%BA%3Ci%3EP%3C%2Fi%3E%5Dbiphenyl%7Drhodium%28I%29+toluene-%3Ci%3Ed%3C%2Fi%3E%3Csub%3E8%3C%2Fsub%3E2.7-solvate&aulast=B%C3%B6rner&aufirst=Armin&rft_id=info%3Adoi%2F10.1107%2Fs2414314616019143&rft.language%5B0%5D=und |
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| author | Selent, Detlef, Spannenberg, Anke, Börner, Armin |
| author_facet | Selent, Detlef, Spannenberg, Anke, Börner, Armin, Selent, Detlef, Spannenberg, Anke, Börner, Armin |
| author_sort | selent, detlef |
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| description | <jats:p>The molecule of the title compound, [Rh(C<jats:sub>42</jats:sub>H<jats:sub>62</jats:sub>O<jats:sub>3</jats:sub>P)(C<jats:sub>74</jats:sub>H<jats:sub>68</jats:sub>O<jats:sub>4</jats:sub>P<jats:sub>2</jats:sub>]·2.7C<jats:sub>7</jats:sub>D<jats:sub>8</jats:sub>, consists of two phospharhodacyclic substructures sharing the Rh atom, which are formed by coordination/<jats:italic>ortho</jats:italic>-metallation of a triaryl phosphite, and by the coordination of a rigid bisphosphite, respectively. The metal displays a tetrahedrally distorted square-planar coordination geometry. A<jats:italic>tert</jats:italic>-butyl group shows rotational disorder over two positions with refined site occupancy of 0.561 (3):0.439 (3). Two partial-occupancy toluene solvent molecules are disordered over two orientations with site occupancies of 0.5:0.3 and 0.5:0.4, respectively. Intramolecular C—H...O hydrogen bonds are observed. In the crystal, complex molecules and toluene solvent molecules pack as alternating layers parallel to the<jats:italic>ac</jats:italic>plane.</jats:p> |
| doi_str_mv | 10.1107/s2414314616019143 |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTEwNy9zMjQxNDMxNDYxNjAxOTE0Mw |
| imprint | International Union of Crystallography (IUCr), 2016 |
| imprint_str_mv | International Union of Crystallography (IUCr), 2016 |
| institution | DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Rs1, DE-Pl11, DE-105, DE-14, DE-Ch1 |
| issn | 2414-3146 |
| issn_str_mv | 2414-3146 |
| language | Undetermined |
| last_indexed | 2024-03-01T13:04:06.108Z |
| match_str | selent20162bis24ditertbutylphenoxyphosphanyloxykp35ditertbutylphenylkc133ditertbutyl55dimethoxy22bis1122tetraphenylethane12dioxyphosphanyloxykpbiphenylrhodiumitoluened827solvate |
| mega_collection | International Union of Crystallography (IUCr) (CrossRef) |
| physical | |
| publishDate | 2016 |
| publishDateSort | 2016 |
| publisher | International Union of Crystallography (IUCr) |
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| spelling | Selent, Detlef Spannenberg, Anke Börner, Armin 2414-3146 International Union of Crystallography (IUCr) General Earth and Planetary Sciences General Environmental Science http://dx.doi.org/10.1107/s2414314616019143 <jats:p>The molecule of the title compound, [Rh(C<jats:sub>42</jats:sub>H<jats:sub>62</jats:sub>O<jats:sub>3</jats:sub>P)(C<jats:sub>74</jats:sub>H<jats:sub>68</jats:sub>O<jats:sub>4</jats:sub>P<jats:sub>2</jats:sub>]·2.7C<jats:sub>7</jats:sub>D<jats:sub>8</jats:sub>, consists of two phospharhodacyclic substructures sharing the Rh atom, which are formed by coordination/<jats:italic>ortho</jats:italic>-metallation of a triaryl phosphite, and by the coordination of a rigid bisphosphite, respectively. The metal displays a tetrahedrally distorted square-planar coordination geometry. A<jats:italic>tert</jats:italic>-butyl group shows rotational disorder over two positions with refined site occupancy of 0.561 (3):0.439 (3). Two partial-occupancy toluene solvent molecules are disordered over two orientations with site occupancies of 0.5:0.3 and 0.5:0.4, respectively. Intramolecular C—H...O hydrogen bonds are observed. In the crystal, complex molecules and toluene solvent molecules pack as alternating layers parallel to the<jats:italic>ac</jats:italic>plane.</jats:p> {2-[Bis(2,4-di-<i>tert</i>-butylphenoxy)phosphanyloxy-κ<i>P</i>]-3,5-di-<i>tert</i>-butylphenyl-κ<i>C</i><sup>1</sup>}{3,3′-di-<i>tert</i>-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κ<i>P</i>]biphenyl}rhodium(I) toluene-<i>d</i><sub>8</sub>2.7-solvate IUCrData |
| spellingShingle | Selent, Detlef, Spannenberg, Anke, Börner, Armin, IUCrData, {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate, General Earth and Planetary Sciences, General Environmental Science |
| title | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_full | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_fullStr | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_full_unstemmed | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_short | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| title_sort | {2-[bis(2,4-di-<i>tert</i>-butylphenoxy)phosphanyloxy-κ<i>p</i>]-3,5-di-<i>tert</i>-butylphenyl-κ<i>c</i><sup>1</sup>}{3,3′-di-<i>tert</i>-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κ<i>p</i>]biphenyl}rhodium(i) toluene-<i>d</i><sub>8</sub>2.7-solvate |
| title_unstemmed | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]biphenyl}rhodium(I) toluene-d82.7-solvate |
| topic | General Earth and Planetary Sciences, General Environmental Science |
| url | http://dx.doi.org/10.1107/s2414314616019143 |