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{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(1,1,2,2-tetraphenylethane-1,2-dioxy)phosphanyloxy-κP]bip...
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| Zeitschriftentitel: | IUCrData |
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| Personen und Körperschaften: | , , |
| In: | IUCrData, 1, 2016, 12 |
| Format: | E-Article |
| Sprache: | Unbestimmt |
| veröffentlicht: |
International Union of Crystallography (IUCr)
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| Schlagwörter: |
| Zusammenfassung: | <jats:p>The molecule of the title compound, [Rh(C<jats:sub>42</jats:sub>H<jats:sub>62</jats:sub>O<jats:sub>3</jats:sub>P)(C<jats:sub>74</jats:sub>H<jats:sub>68</jats:sub>O<jats:sub>4</jats:sub>P<jats:sub>2</jats:sub>]·2.7C<jats:sub>7</jats:sub>D<jats:sub>8</jats:sub>, consists of two phospharhodacyclic substructures sharing the Rh atom, which are formed by coordination/<jats:italic>ortho</jats:italic>-metallation of a triaryl phosphite, and by the coordination of a rigid bisphosphite, respectively. The metal displays a tetrahedrally distorted square-planar coordination geometry. A<jats:italic>tert</jats:italic>-butyl group shows rotational disorder over two positions with refined site occupancy of 0.561 (3):0.439 (3). Two partial-occupancy toluene solvent molecules are disordered over two orientations with site occupancies of 0.5:0.3 and 0.5:0.4, respectively. Intramolecular C—H...O hydrogen bonds are observed. In the crystal, complex molecules and toluene solvent molecules pack as alternating layers parallel to the<jats:italic>ac</jats:italic>plane.</jats:p> |
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| ISSN: |
2414-3146
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| DOI: | 10.1107/s2414314616019143 |