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One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants
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Zeitschriftentitel: | Materials |
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Personen und Körperschaften: | , , , |
In: | Materials, 12, 2019, 14, S. 2297 |
Format: | E-Article |
Sprache: | Englisch |
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MDPI AG
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author_facet |
Akbarzadeh, Rokhsareh Asadi, Anvar Oviroh, Peter Ozaveshe Jen, Tien-Chien Akbarzadeh, Rokhsareh Asadi, Anvar Oviroh, Peter Ozaveshe Jen, Tien-Chien |
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author |
Akbarzadeh, Rokhsareh Asadi, Anvar Oviroh, Peter Ozaveshe Jen, Tien-Chien |
spellingShingle |
Akbarzadeh, Rokhsareh Asadi, Anvar Oviroh, Peter Ozaveshe Jen, Tien-Chien Materials One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants General Materials Science |
author_sort |
akbarzadeh, rokhsareh |
spelling |
Akbarzadeh, Rokhsareh Asadi, Anvar Oviroh, Peter Ozaveshe Jen, Tien-Chien 1996-1944 MDPI AG General Materials Science http://dx.doi.org/10.3390/ma12142297 <jats:p>A novel enhanced visible light absorption BiOCl/AgCl/BiVO4 heterojunction of photocatalysts could be obtained through a one-pot hydrothermal method used with two different pH solutions. There was a relationship between synthesis pH and the ratio of BiOCl to BiVO4 in XRD planes and their photocatalytic activity. The visible light photocatalytic performances of photocatalysts were evaluated via degradation of diclofenac (DCFF) as a pharmaceutical model pollutant. Furthermore, kinetic studies showed that DCF degradation followed pseudo-first-order kinetics. The photocatalytic degradation rates of BiOCl/AgCl/BiVO4 synthesized at pH = 1.2 and pH = 4 for DCF were 72% and 47%, respectively, showing the higher activity of the photocatalyst which was synthesized at a lower pH value. It was concluded that the excellent photocatalytic activity of BiOCl/AgCl/BiVO4 is due to the enhanced visible light absorption formation of a heterostructure, which increased the lifetime of photo-produced electron–hole pairs by creating a heterojunction. The influence of pH during synthesis on photocatalytic activity in order to create different phases was investigated. This work suggests that the BiOCl/AgCl/BiVO4 p-n heterojunction is more active when the ratio of BiOCl to BiVO4 is smaller, and this could be achieved simply by the pH adjustment. This is a promising method of modifying the photocatalyst for the purpose of pollutant degradation under visible light illumination.</jats:p> One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants Materials |
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10.3390/ma12142297 |
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MDPI AG, 2019 |
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MDPI AG, 2019 |
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title |
One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_unstemmed |
One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_full |
One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_fullStr |
One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_full_unstemmed |
One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_short |
One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_sort |
one-pot synthesized visible light-driven biocl/agcl/bivo4 n-p heterojunction for photocatalytic degradation of pharmaceutical pollutants |
topic |
General Materials Science |
url |
http://dx.doi.org/10.3390/ma12142297 |
publishDate |
2019 |
physical |
2297 |
description |
<jats:p>A novel enhanced visible light absorption BiOCl/AgCl/BiVO4 heterojunction of photocatalysts could be obtained through a one-pot hydrothermal method used with two different pH solutions. There was a relationship between synthesis pH and the ratio of BiOCl to BiVO4 in XRD planes and their photocatalytic activity. The visible light photocatalytic performances of photocatalysts were evaluated via degradation of diclofenac (DCFF) as a pharmaceutical model pollutant. Furthermore, kinetic studies showed that DCF degradation followed pseudo-first-order kinetics. The photocatalytic degradation rates of BiOCl/AgCl/BiVO4 synthesized at pH = 1.2 and pH = 4 for DCF were 72% and 47%, respectively, showing the higher activity of the photocatalyst which was synthesized at a lower pH value. It was concluded that the excellent photocatalytic activity of BiOCl/AgCl/BiVO4 is due to the enhanced visible light absorption formation of a heterostructure, which increased the lifetime of photo-produced electron–hole pairs by creating a heterojunction. The influence of pH during synthesis on photocatalytic activity in order to create different phases was investigated. This work suggests that the BiOCl/AgCl/BiVO4 p-n heterojunction is more active when the ratio of BiOCl to BiVO4 is smaller, and this could be achieved simply by the pH adjustment. This is a promising method of modifying the photocatalyst for the purpose of pollutant degradation under visible light illumination.</jats:p> |
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author | Akbarzadeh, Rokhsareh, Asadi, Anvar, Oviroh, Peter Ozaveshe, Jen, Tien-Chien |
author_facet | Akbarzadeh, Rokhsareh, Asadi, Anvar, Oviroh, Peter Ozaveshe, Jen, Tien-Chien, Akbarzadeh, Rokhsareh, Asadi, Anvar, Oviroh, Peter Ozaveshe, Jen, Tien-Chien |
author_sort | akbarzadeh, rokhsareh |
container_issue | 14 |
container_start_page | 0 |
container_title | Materials |
container_volume | 12 |
description | <jats:p>A novel enhanced visible light absorption BiOCl/AgCl/BiVO4 heterojunction of photocatalysts could be obtained through a one-pot hydrothermal method used with two different pH solutions. There was a relationship between synthesis pH and the ratio of BiOCl to BiVO4 in XRD planes and their photocatalytic activity. The visible light photocatalytic performances of photocatalysts were evaluated via degradation of diclofenac (DCFF) as a pharmaceutical model pollutant. Furthermore, kinetic studies showed that DCF degradation followed pseudo-first-order kinetics. The photocatalytic degradation rates of BiOCl/AgCl/BiVO4 synthesized at pH = 1.2 and pH = 4 for DCF were 72% and 47%, respectively, showing the higher activity of the photocatalyst which was synthesized at a lower pH value. It was concluded that the excellent photocatalytic activity of BiOCl/AgCl/BiVO4 is due to the enhanced visible light absorption formation of a heterostructure, which increased the lifetime of photo-produced electron–hole pairs by creating a heterojunction. The influence of pH during synthesis on photocatalytic activity in order to create different phases was investigated. This work suggests that the BiOCl/AgCl/BiVO4 p-n heterojunction is more active when the ratio of BiOCl to BiVO4 is smaller, and this could be achieved simply by the pH adjustment. This is a promising method of modifying the photocatalyst for the purpose of pollutant degradation under visible light illumination.</jats:p> |
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source_id | 49 |
spelling | Akbarzadeh, Rokhsareh Asadi, Anvar Oviroh, Peter Ozaveshe Jen, Tien-Chien 1996-1944 MDPI AG General Materials Science http://dx.doi.org/10.3390/ma12142297 <jats:p>A novel enhanced visible light absorption BiOCl/AgCl/BiVO4 heterojunction of photocatalysts could be obtained through a one-pot hydrothermal method used with two different pH solutions. There was a relationship between synthesis pH and the ratio of BiOCl to BiVO4 in XRD planes and their photocatalytic activity. The visible light photocatalytic performances of photocatalysts were evaluated via degradation of diclofenac (DCFF) as a pharmaceutical model pollutant. Furthermore, kinetic studies showed that DCF degradation followed pseudo-first-order kinetics. The photocatalytic degradation rates of BiOCl/AgCl/BiVO4 synthesized at pH = 1.2 and pH = 4 for DCF were 72% and 47%, respectively, showing the higher activity of the photocatalyst which was synthesized at a lower pH value. It was concluded that the excellent photocatalytic activity of BiOCl/AgCl/BiVO4 is due to the enhanced visible light absorption formation of a heterostructure, which increased the lifetime of photo-produced electron–hole pairs by creating a heterojunction. The influence of pH during synthesis on photocatalytic activity in order to create different phases was investigated. This work suggests that the BiOCl/AgCl/BiVO4 p-n heterojunction is more active when the ratio of BiOCl to BiVO4 is smaller, and this could be achieved simply by the pH adjustment. This is a promising method of modifying the photocatalyst for the purpose of pollutant degradation under visible light illumination.</jats:p> One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants Materials |
spellingShingle | Akbarzadeh, Rokhsareh, Asadi, Anvar, Oviroh, Peter Ozaveshe, Jen, Tien-Chien, Materials, One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants, General Materials Science |
title | One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_full | One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_fullStr | One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_full_unstemmed | One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_short | One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
title_sort | one-pot synthesized visible light-driven biocl/agcl/bivo4 n-p heterojunction for photocatalytic degradation of pharmaceutical pollutants |
title_unstemmed | One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO4 n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants |
topic | General Materials Science |
url | http://dx.doi.org/10.3390/ma12142297 |