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Syntheses and characterization of new dithiophosphinato zinc complexes
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| Zeitschriftentitel: | Journal of the Turkish Chemical Society Section A: Chemistry |
|---|---|
| Personen und Körperschaften: | , |
| In: | Journal of the Turkish Chemical Society Section A: Chemistry, 5, 2018, 2, S. 931-940 |
| Format: | E-Article |
| Sprache: | Unbestimmt |
| veröffentlicht: |
The Turkish Chemical Society
|
| Schlagwörter: |
| author_facet |
SAĞLAM, Ertuğrul Gazi ACAR, Nurcan SAĞLAM, Ertuğrul Gazi ACAR, Nurcan |
|---|---|
| author |
SAĞLAM, Ertuğrul Gazi ACAR, Nurcan |
| spellingShingle |
SAĞLAM, Ertuğrul Gazi ACAR, Nurcan Journal of the Turkish Chemical Society Section A: Chemistry Syntheses and characterization of new dithiophosphinato zinc complexes General Chemistry |
| author_sort |
sağlam, ertuğrul gazi |
| spelling |
SAĞLAM, Ertuğrul Gazi ACAR, Nurcan 2149-0120 The Turkish Chemical Society General Chemistry http://dx.doi.org/10.18596/jotcsa.427192 <jats:p xml:lang="en">Four known dithiophosphinic acids, DTPA, were synthesized and their zinc complexes were prepared as novelties. The complexes have been proven to have the structures [Zn(µ-DTPAn)2(DTPAn)2], ([DTPAn]= Rn(R)P(S)H, R= 4-CH3O-C6H4-; R1= iso-amyl-, DTPA1; R2= iso-butyl-, DTPA2; R3= sec-butyl-, DTPA3; R4= iso-propyl-, DTPA4). The DTPAs were prepared by the reaction of the Lawesson reagent, [2,4–bis(4-methoxyphenyl)–1,3,2,4–ditiyodifosfetan–2,4–disülfür] (LR), with the corresponding Grignard compounds. The acids formed are viscous liquids difficult to purify and so they were converted to ammonium salts, [DTPAn][NH4], which are easy to obtain as pure crystals. The complexes were identified to have dimeric structures on the basis of mass spectroscopic data.</jats:p> Syntheses and characterization of new dithiophosphinato zinc complexes Journal of the Turkish Chemical Society Section A: Chemistry |
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The Turkish Chemical Society, 2018 |
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The Turkish Chemical Society, 2018 |
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2018 |
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The Turkish Chemical Society |
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Journal of the Turkish Chemical Society Section A: Chemistry |
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49 |
| title |
Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_unstemmed |
Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_full |
Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_fullStr |
Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_full_unstemmed |
Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_short |
Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_sort |
syntheses and characterization of new dithiophosphinato zinc complexes |
| topic |
General Chemistry |
| url |
http://dx.doi.org/10.18596/jotcsa.427192 |
| publishDate |
2018 |
| physical |
931-940 |
| description |
<jats:p xml:lang="en">Four known dithiophosphinic
acids, DTPA, were synthesized and their zinc complexes were prepared as
novelties. The complexes have been proven to have the structures [Zn(µ-DTPAn)2(DTPAn)2],
([DTPAn]= Rn(R)P(S)H, R= 4-CH3O-C6H4-;
R1= iso-amyl-, DTPA1; R2= iso-butyl-,
DTPA2; R3= sec-butyl-, DTPA3; R4=
iso-propyl-, DTPA4). The DTPAs were prepared by the reaction
of the Lawesson
reagent, [2,4–bis(4-methoxyphenyl)–1,3,2,4–ditiyodifosfetan–2,4–disülfür] (LR),
with the corresponding Grignard compounds. The acids formed are viscous liquids
difficult to purify and so they were converted to ammonium salts, [DTPAn][NH4],
which are easy to obtain as pure crystals. The complexes were identified to
have dimeric structures on the basis of mass spectroscopic data.</jats:p> |
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| author | SAĞLAM, Ertuğrul Gazi, ACAR, Nurcan |
| author_facet | SAĞLAM, Ertuğrul Gazi, ACAR, Nurcan, SAĞLAM, Ertuğrul Gazi, ACAR, Nurcan |
| author_sort | sağlam, ertuğrul gazi |
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| description | <jats:p xml:lang="en">Four known dithiophosphinic acids, DTPA, were synthesized and their zinc complexes were prepared as novelties. The complexes have been proven to have the structures [Zn(µ-DTPAn)2(DTPAn)2], ([DTPAn]= Rn(R)P(S)H, R= 4-CH3O-C6H4-; R1= iso-amyl-, DTPA1; R2= iso-butyl-, DTPA2; R3= sec-butyl-, DTPA3; R4= iso-propyl-, DTPA4). The DTPAs were prepared by the reaction of the Lawesson reagent, [2,4–bis(4-methoxyphenyl)–1,3,2,4–ditiyodifosfetan–2,4–disülfür] (LR), with the corresponding Grignard compounds. The acids formed are viscous liquids difficult to purify and so they were converted to ammonium salts, [DTPAn][NH4], which are easy to obtain as pure crystals. The complexes were identified to have dimeric structures on the basis of mass spectroscopic data.</jats:p> |
| doi_str_mv | 10.18596/jotcsa.427192 |
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| imprint_str_mv | The Turkish Chemical Society, 2018 |
| institution | DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229 |
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| physical | 931-940 |
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| series | Journal of the Turkish Chemical Society Section A: Chemistry |
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| spelling | SAĞLAM, Ertuğrul Gazi ACAR, Nurcan 2149-0120 The Turkish Chemical Society General Chemistry http://dx.doi.org/10.18596/jotcsa.427192 <jats:p xml:lang="en">Four known dithiophosphinic acids, DTPA, were synthesized and their zinc complexes were prepared as novelties. The complexes have been proven to have the structures [Zn(µ-DTPAn)2(DTPAn)2], ([DTPAn]= Rn(R)P(S)H, R= 4-CH3O-C6H4-; R1= iso-amyl-, DTPA1; R2= iso-butyl-, DTPA2; R3= sec-butyl-, DTPA3; R4= iso-propyl-, DTPA4). The DTPAs were prepared by the reaction of the Lawesson reagent, [2,4–bis(4-methoxyphenyl)–1,3,2,4–ditiyodifosfetan–2,4–disülfür] (LR), with the corresponding Grignard compounds. The acids formed are viscous liquids difficult to purify and so they were converted to ammonium salts, [DTPAn][NH4], which are easy to obtain as pure crystals. The complexes were identified to have dimeric structures on the basis of mass spectroscopic data.</jats:p> Syntheses and characterization of new dithiophosphinato zinc complexes Journal of the Turkish Chemical Society Section A: Chemistry |
| spellingShingle | SAĞLAM, Ertuğrul Gazi, ACAR, Nurcan, Journal of the Turkish Chemical Society Section A: Chemistry, Syntheses and characterization of new dithiophosphinato zinc complexes, General Chemistry |
| title | Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_full | Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_fullStr | Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_full_unstemmed | Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_short | Syntheses and characterization of new dithiophosphinato zinc complexes |
| title_sort | syntheses and characterization of new dithiophosphinato zinc complexes |
| title_unstemmed | Syntheses and characterization of new dithiophosphinato zinc complexes |
| topic | General Chemistry |
| url | http://dx.doi.org/10.18596/jotcsa.427192 |