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Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides
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Zeitschriftentitel: | Zeitschrift für Naturforschung B |
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Personen und Körperschaften: | , , |
In: | Zeitschrift für Naturforschung B, 54, 1999, 7, S. 858-862 |
Format: | E-Article |
Sprache: | Englisch |
veröffentlicht: |
Walter de Gruyter GmbH
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Schlagwörter: |
author_facet |
Braun, Thomas P. Gutsch, Paul A. Zimmer, Hans Braun, Thomas P. Gutsch, Paul A. Zimmer, Hans |
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author |
Braun, Thomas P. Gutsch, Paul A. Zimmer, Hans |
spellingShingle |
Braun, Thomas P. Gutsch, Paul A. Zimmer, Hans Zeitschrift für Naturforschung B Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides General Chemistry |
author_sort |
braun, thomas p. |
spelling |
Braun, Thomas P. Gutsch, Paul A. Zimmer, Hans 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1999-0706 <jats:p>The synthesis, IR and <jats:sup>31</jats:sup>P NMR spectra of the complexes of various N-aryltriphenylphosphinimines with some mercury dihalides as well as the corresponding phosphonium salts are reported. It is shown by an X-ray crystal structure analysis of the complex of the unsubstituted phosphinimine with HgCl<jats:sub>2</jats:sub> that in the solid state these complexes form dimers via two Hg ∙∙∙ μ<jats:sub>2</jats:sub>- Cl ∙∙∙ Hg bridges.</jats:p> Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides Zeitschrift für Naturforschung B |
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10.1515/znb-1999-0706 |
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1999 |
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Walter de Gruyter GmbH |
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Zeitschrift für Naturforschung B |
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title |
Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_unstemmed |
Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_full |
Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_fullStr |
Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_full_unstemmed |
Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_short |
Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_sort |
complexes of n-aryltriphenylphosphinimines with mercury(ii) halides |
topic |
General Chemistry |
url |
http://dx.doi.org/10.1515/znb-1999-0706 |
publishDate |
1999 |
physical |
858-862 |
description |
<jats:p>The synthesis, IR and <jats:sup>31</jats:sup>P NMR spectra of the complexes of various N-aryltriphenylphosphinimines with some mercury dihalides as well as the corresponding phosphonium salts are reported. It is shown by an X-ray crystal structure analysis of the complex of the unsubstituted phosphinimine with HgCl<jats:sub>2</jats:sub> that in the solid state these complexes form dimers via two Hg ∙∙∙ μ<jats:sub>2</jats:sub>- Cl ∙∙∙ Hg bridges.</jats:p> |
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author | Braun, Thomas P., Gutsch, Paul A., Zimmer, Hans |
author_facet | Braun, Thomas P., Gutsch, Paul A., Zimmer, Hans, Braun, Thomas P., Gutsch, Paul A., Zimmer, Hans |
author_sort | braun, thomas p. |
container_issue | 7 |
container_start_page | 858 |
container_title | Zeitschrift für Naturforschung B |
container_volume | 54 |
description | <jats:p>The synthesis, IR and <jats:sup>31</jats:sup>P NMR spectra of the complexes of various N-aryltriphenylphosphinimines with some mercury dihalides as well as the corresponding phosphonium salts are reported. It is shown by an X-ray crystal structure analysis of the complex of the unsubstituted phosphinimine with HgCl<jats:sub>2</jats:sub> that in the solid state these complexes form dimers via two Hg ∙∙∙ μ<jats:sub>2</jats:sub>- Cl ∙∙∙ Hg bridges.</jats:p> |
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imprint | Walter de Gruyter GmbH, 1999 |
imprint_str_mv | Walter de Gruyter GmbH, 1999 |
institution | DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Rs1, DE-Pl11, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1 |
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physical | 858-862 |
publishDate | 1999 |
publishDateSort | 1999 |
publisher | Walter de Gruyter GmbH |
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recordtype | ai |
series | Zeitschrift für Naturforschung B |
source_id | 49 |
spelling | Braun, Thomas P. Gutsch, Paul A. Zimmer, Hans 1865-7117 0932-0776 Walter de Gruyter GmbH General Chemistry http://dx.doi.org/10.1515/znb-1999-0706 <jats:p>The synthesis, IR and <jats:sup>31</jats:sup>P NMR spectra of the complexes of various N-aryltriphenylphosphinimines with some mercury dihalides as well as the corresponding phosphonium salts are reported. It is shown by an X-ray crystal structure analysis of the complex of the unsubstituted phosphinimine with HgCl<jats:sub>2</jats:sub> that in the solid state these complexes form dimers via two Hg ∙∙∙ μ<jats:sub>2</jats:sub>- Cl ∙∙∙ Hg bridges.</jats:p> Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides Zeitschrift für Naturforschung B |
spellingShingle | Braun, Thomas P., Gutsch, Paul A., Zimmer, Hans, Zeitschrift für Naturforschung B, Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides, General Chemistry |
title | Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_full | Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_fullStr | Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_full_unstemmed | Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_short | Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
title_sort | complexes of n-aryltriphenylphosphinimines with mercury(ii) halides |
title_unstemmed | Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides |
topic | General Chemistry |
url | http://dx.doi.org/10.1515/znb-1999-0706 |