Details
Zusammenfassung: <jats:p>The first Re NQR spectra of rhenium oxygen compounds with rhenium atoms in the pseudo-octahedral environment of Re<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>(H<jats:sub>2</jats:sub>O)<jats:sub>2</jats:sub> and Re<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>(H<jats:sub>2</jats:sub>O)<jats:sub>2</jats:sub> · 2(1,4)-dioxane were found. The values of the Re NQR coupling constants of these rhenium atoms are the highest measured until now. They show, that the gradient of the electrical field is much more sensitive to distortions of an octahedral crystal field than to distortions of a tetrahedral field. </jats:p>
Umfang: 896-898
ISSN: 1865-7117
0932-0776
DOI: 10.1515/znb-1978-0816