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Feld-und Oberflächenreaktionen der Olefine
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Zeitschriftentitel: | Zeitschrift für Naturforschung A |
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Personen und Körperschaften: | , , |
In: | Zeitschrift für Naturforschung A, 28, 1973, 1, S. 60-68 |
Format: | E-Article |
Sprache: | Unbestimmt |
veröffentlicht: |
Walter de Gruyter GmbH
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Schlagwörter: |
author_facet |
Okuyama, F. Röllgen, F. W. Beckey, H. D. Okuyama, F. Röllgen, F. W. Beckey, H. D. |
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author |
Okuyama, F. Röllgen, F. W. Beckey, H. D. |
spellingShingle |
Okuyama, F. Röllgen, F. W. Beckey, H. D. Zeitschrift für Naturforschung A Feld-und Oberflächenreaktionen der Olefine Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics |
author_sort |
okuyama, f. |
spelling |
Okuyama, F. Röllgen, F. W. Beckey, H. D. 1865-7109 0932-0784 Walter de Gruyter GmbH Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics http://dx.doi.org/10.1515/zna-1973-0112 <jats:p>The dependence of the field ionization behaviour of olefines on field-induced surface reactions is demonstrated using 1-Hexene as an example. Different emitter- and field strength dependent reaction mechanisms leading to the production of (M+1)<jats:sup>+</jats:sup> and (M-1)<jats:sup>+</jats:sup> ions may be distinguished. The characteristics of define spectra taken using activated emitters are determined largely by surface induced reactions which appear at higher field strengths. These have as their starting point an ionic field adsorption of the olefine. In particular the field enhancement of the organic microneedles is strongly influenced by field adsorbed ions so that field dissociation products are also measured with increased intensity.</jats:p> Feld-und Oberflächenreaktionen der Olefine Zeitschrift für Naturforschung A |
doi_str_mv |
10.1515/zna-1973-0112 |
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Chemie und Pharmazie Physik Mathematik |
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Walter de Gruyter GmbH, 1973 |
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Walter de Gruyter GmbH, 1973 |
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1865-7109 0932-0784 |
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1865-7109 0932-0784 |
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Walter de Gruyter GmbH (CrossRef) |
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1973 |
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Walter de Gruyter GmbH |
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Zeitschrift für Naturforschung A |
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49 |
title |
Feld-und Oberflächenreaktionen der Olefine |
title_unstemmed |
Feld-und Oberflächenreaktionen der Olefine |
title_full |
Feld-und Oberflächenreaktionen der Olefine |
title_fullStr |
Feld-und Oberflächenreaktionen der Olefine |
title_full_unstemmed |
Feld-und Oberflächenreaktionen der Olefine |
title_short |
Feld-und Oberflächenreaktionen der Olefine |
title_sort |
feld-und oberflächenreaktionen der olefine |
topic |
Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics |
url |
http://dx.doi.org/10.1515/zna-1973-0112 |
publishDate |
1973 |
physical |
60-68 |
description |
<jats:p>The dependence of the field ionization behaviour of olefines on field-induced surface reactions is demonstrated using 1-Hexene as an example. Different emitter- and field strength dependent reaction mechanisms leading to the production of (M+1)<jats:sup>+</jats:sup> and (M-1)<jats:sup>+</jats:sup> ions may be distinguished. The characteristics of define spectra taken using activated emitters are determined largely by surface induced reactions which appear at higher field strengths. These have as their starting point an ionic field adsorption of the olefine. In particular the field enhancement of the organic microneedles is strongly influenced by field adsorbed ions so that field dissociation products are also measured with increased intensity.</jats:p> |
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author | Okuyama, F., Röllgen, F. W., Beckey, H. D. |
author_facet | Okuyama, F., Röllgen, F. W., Beckey, H. D., Okuyama, F., Röllgen, F. W., Beckey, H. D. |
author_sort | okuyama, f. |
container_issue | 1 |
container_start_page | 60 |
container_title | Zeitschrift für Naturforschung A |
container_volume | 28 |
description | <jats:p>The dependence of the field ionization behaviour of olefines on field-induced surface reactions is demonstrated using 1-Hexene as an example. Different emitter- and field strength dependent reaction mechanisms leading to the production of (M+1)<jats:sup>+</jats:sup> and (M-1)<jats:sup>+</jats:sup> ions may be distinguished. The characteristics of define spectra taken using activated emitters are determined largely by surface induced reactions which appear at higher field strengths. These have as their starting point an ionic field adsorption of the olefine. In particular the field enhancement of the organic microneedles is strongly influenced by field adsorbed ions so that field dissociation products are also measured with increased intensity.</jats:p> |
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imprint | Walter de Gruyter GmbH, 1973 |
imprint_str_mv | Walter de Gruyter GmbH, 1973 |
institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Zwi2 |
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physical | 60-68 |
publishDate | 1973 |
publishDateSort | 1973 |
publisher | Walter de Gruyter GmbH |
record_format | ai |
recordtype | ai |
series | Zeitschrift für Naturforschung A |
source_id | 49 |
spelling | Okuyama, F. Röllgen, F. W. Beckey, H. D. 1865-7109 0932-0784 Walter de Gruyter GmbH Physical and Theoretical Chemistry General Physics and Astronomy Mathematical Physics http://dx.doi.org/10.1515/zna-1973-0112 <jats:p>The dependence of the field ionization behaviour of olefines on field-induced surface reactions is demonstrated using 1-Hexene as an example. Different emitter- and field strength dependent reaction mechanisms leading to the production of (M+1)<jats:sup>+</jats:sup> and (M-1)<jats:sup>+</jats:sup> ions may be distinguished. The characteristics of define spectra taken using activated emitters are determined largely by surface induced reactions which appear at higher field strengths. These have as their starting point an ionic field adsorption of the olefine. In particular the field enhancement of the organic microneedles is strongly influenced by field adsorbed ions so that field dissociation products are also measured with increased intensity.</jats:p> Feld-und Oberflächenreaktionen der Olefine Zeitschrift für Naturforschung A |
spellingShingle | Okuyama, F., Röllgen, F. W., Beckey, H. D., Zeitschrift für Naturforschung A, Feld-und Oberflächenreaktionen der Olefine, Physical and Theoretical Chemistry, General Physics and Astronomy, Mathematical Physics |
title | Feld-und Oberflächenreaktionen der Olefine |
title_full | Feld-und Oberflächenreaktionen der Olefine |
title_fullStr | Feld-und Oberflächenreaktionen der Olefine |
title_full_unstemmed | Feld-und Oberflächenreaktionen der Olefine |
title_short | Feld-und Oberflächenreaktionen der Olefine |
title_sort | feld-und oberflächenreaktionen der olefine |
title_unstemmed | Feld-und Oberflächenreaktionen der Olefine |
topic | Physical and Theoretical Chemistry, General Physics and Astronomy, Mathematical Physics |
url | http://dx.doi.org/10.1515/zna-1973-0112 |