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Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I)
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| Zeitschriftentitel: | Canadian Journal of Chemistry |
|---|---|
| Personen und Körperschaften: | , |
| In: | Canadian Journal of Chemistry, 50, 1972, 7, S. 999-1004 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Canadian Science Publishing
|
| Schlagwörter: |
| author_facet |
Leh, F. Wan, J. K. S. Leh, F. Wan, J. K. S. |
|---|---|
| author |
Leh, F. Wan, J. K. S. |
| spellingShingle |
Leh, F. Wan, J. K. S. Canadian Journal of Chemistry Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) Organic Chemistry General Chemistry Catalysis |
| author_sort |
leh, f. |
| spelling |
Leh, F. Wan, J. K. S. 0008-4042 1480-3291 Canadian Science Publishing Organic Chemistry General Chemistry Catalysis http://dx.doi.org/10.1139/v72-157 <jats:p> Reactions of Cu(I)Cl, Cu(II)Cl<jats:sub>2</jats:sub>, Cu(II) acetylacetonates, and Cu(II) N-methylsalicylalidiiminate with the stable free radical 2,2-diphenyl-1-picrylhydrazyl have been investigated. In all cases Cu(II) was reduced and the organic radical behaved as an electron donor-ligand to form complexes containing Cu(I). These novel free radical Cu(I) complexes were characterized by various spectroscopic methods, including e.s.r. </jats:p> Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) Canadian Journal of Chemistry |
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Canadian Science Publishing, 1972 |
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Canadian Science Publishing, 1972 |
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0008-4042 1480-3291 |
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Canadian Science Publishing |
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Canadian Journal of Chemistry |
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| title |
Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_unstemmed |
Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_full |
Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_fullStr |
Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_full_unstemmed |
Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_short |
Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_sort |
organic free radical and metal complexes. 2,2-diphenyl-1-picrylhydrazyl with cu(i) |
| topic |
Organic Chemistry General Chemistry Catalysis |
| url |
http://dx.doi.org/10.1139/v72-157 |
| publishDate |
1972 |
| physical |
999-1004 |
| description |
<jats:p> Reactions of Cu(I)Cl, Cu(II)Cl<jats:sub>2</jats:sub>, Cu(II) acetylacetonates, and Cu(II) N-methylsalicylalidiiminate with the stable free radical 2,2-diphenyl-1-picrylhydrazyl have been investigated. In all cases Cu(II) was reduced and the organic radical behaved as an electron donor-ligand to form complexes containing Cu(I). These novel free radical Cu(I) complexes were characterized by various spectroscopic methods, including e.s.r. </jats:p> |
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| author | Leh, F., Wan, J. K. S. |
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| container_title | Canadian Journal of Chemistry |
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| description | <jats:p> Reactions of Cu(I)Cl, Cu(II)Cl<jats:sub>2</jats:sub>, Cu(II) acetylacetonates, and Cu(II) N-methylsalicylalidiiminate with the stable free radical 2,2-diphenyl-1-picrylhydrazyl have been investigated. In all cases Cu(II) was reduced and the organic radical behaved as an electron donor-ligand to form complexes containing Cu(I). These novel free radical Cu(I) complexes were characterized by various spectroscopic methods, including e.s.r. </jats:p> |
| doi_str_mv | 10.1139/v72-157 |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTEzOS92NzItMTU3 |
| imprint | Canadian Science Publishing, 1972 |
| imprint_str_mv | Canadian Science Publishing, 1972 |
| institution | DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1 |
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| physical | 999-1004 |
| publishDate | 1972 |
| publishDateSort | 1972 |
| publisher | Canadian Science Publishing |
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| recordtype | ai |
| series | Canadian Journal of Chemistry |
| source_id | 49 |
| spelling | Leh, F. Wan, J. K. S. 0008-4042 1480-3291 Canadian Science Publishing Organic Chemistry General Chemistry Catalysis http://dx.doi.org/10.1139/v72-157 <jats:p> Reactions of Cu(I)Cl, Cu(II)Cl<jats:sub>2</jats:sub>, Cu(II) acetylacetonates, and Cu(II) N-methylsalicylalidiiminate with the stable free radical 2,2-diphenyl-1-picrylhydrazyl have been investigated. In all cases Cu(II) was reduced and the organic radical behaved as an electron donor-ligand to form complexes containing Cu(I). These novel free radical Cu(I) complexes were characterized by various spectroscopic methods, including e.s.r. </jats:p> Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) Canadian Journal of Chemistry |
| spellingShingle | Leh, F., Wan, J. K. S., Canadian Journal of Chemistry, Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I), Organic Chemistry, General Chemistry, Catalysis |
| title | Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_full | Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_fullStr | Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_full_unstemmed | Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_short | Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| title_sort | organic free radical and metal complexes. 2,2-diphenyl-1-picrylhydrazyl with cu(i) |
| title_unstemmed | Organic Free Radical and Metal Complexes. 2,2-Diphenyl-1-picrylhydrazyl with Cu(I) |
| topic | Organic Chemistry, General Chemistry, Catalysis |
| url | http://dx.doi.org/10.1139/v72-157 |