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Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series
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| Zeitschriftentitel: | Canadian Journal of Chemistry |
|---|---|
| Personen und Körperschaften: | , |
| In: | Canadian Journal of Chemistry, 46, 1968, 9, S. 1583-1586 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Canadian Science Publishing
|
| Schlagwörter: |
| author_facet |
Still, Ian W. J. Wang, D. T. Still, Ian W. J. Wang, D. T. |
|---|---|
| author |
Still, Ian W. J. Wang, D. T. |
| spellingShingle |
Still, Ian W. J. Wang, D. T. Canadian Journal of Chemistry Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series Organic Chemistry General Chemistry Catalysis |
| author_sort |
still, ian w. j. |
| spelling |
Still, Ian W. J. Wang, D. T. 0008-4042 1480-3291 Canadian Science Publishing Organic Chemistry General Chemistry Catalysis http://dx.doi.org/10.1139/v68-262 <jats:p> The photochemical and thermal decomposition reactions of 5-diazo-3-caren-2-one have been studied. Thermal decomposition led to the corresponding azine (93 %), while photochemical decomposition in aqueous dioxan led to the azine (7%) and to 3-carene-2,5-dione (9%). Photochemical decomposition in methanol led to a third product C<jats:sub>20</jats:sub>H<jats:sub>24</jats:sub>O<jats:sub>4</jats:sub> (3%). Experiments on the photochemical decomposition of the isomeric 2-diazo-3-caren-5-one are also described. </jats:p> Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series Canadian Journal of Chemistry |
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Canadian Science Publishing, 1968 |
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Canadian Science Publishing, 1968 |
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0008-4042 1480-3291 |
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1968 |
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Canadian Science Publishing |
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Canadian Journal of Chemistry |
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49 |
| title |
Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_unstemmed |
Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_full |
Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_fullStr |
Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_full_unstemmed |
Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_short |
Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_sort |
thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| topic |
Organic Chemistry General Chemistry Catalysis |
| url |
http://dx.doi.org/10.1139/v68-262 |
| publishDate |
1968 |
| physical |
1583-1586 |
| description |
<jats:p> The photochemical and thermal decomposition reactions of 5-diazo-3-caren-2-one have been studied. Thermal decomposition led to the corresponding azine (93 %), while photochemical decomposition in aqueous dioxan led to the azine (7%) and to 3-carene-2,5-dione (9%). Photochemical decomposition in methanol led to a third product C<jats:sub>20</jats:sub>H<jats:sub>24</jats:sub>O<jats:sub>4</jats:sub> (3%). Experiments on the photochemical decomposition of the isomeric 2-diazo-3-caren-5-one are also described. </jats:p> |
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| author | Still, Ian W. J., Wang, D. T. |
| author_facet | Still, Ian W. J., Wang, D. T., Still, Ian W. J., Wang, D. T. |
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| container_title | Canadian Journal of Chemistry |
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| description | <jats:p> The photochemical and thermal decomposition reactions of 5-diazo-3-caren-2-one have been studied. Thermal decomposition led to the corresponding azine (93 %), while photochemical decomposition in aqueous dioxan led to the azine (7%) and to 3-carene-2,5-dione (9%). Photochemical decomposition in methanol led to a third product C<jats:sub>20</jats:sub>H<jats:sub>24</jats:sub>O<jats:sub>4</jats:sub> (3%). Experiments on the photochemical decomposition of the isomeric 2-diazo-3-caren-5-one are also described. </jats:p> |
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| imprint | Canadian Science Publishing, 1968 |
| imprint_str_mv | Canadian Science Publishing, 1968 |
| institution | DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3 |
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| publisher | Canadian Science Publishing |
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| series | Canadian Journal of Chemistry |
| source_id | 49 |
| spelling | Still, Ian W. J. Wang, D. T. 0008-4042 1480-3291 Canadian Science Publishing Organic Chemistry General Chemistry Catalysis http://dx.doi.org/10.1139/v68-262 <jats:p> The photochemical and thermal decomposition reactions of 5-diazo-3-caren-2-one have been studied. Thermal decomposition led to the corresponding azine (93 %), while photochemical decomposition in aqueous dioxan led to the azine (7%) and to 3-carene-2,5-dione (9%). Photochemical decomposition in methanol led to a third product C<jats:sub>20</jats:sub>H<jats:sub>24</jats:sub>O<jats:sub>4</jats:sub> (3%). Experiments on the photochemical decomposition of the isomeric 2-diazo-3-caren-5-one are also described. </jats:p> Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series Canadian Journal of Chemistry |
| spellingShingle | Still, Ian W. J., Wang, D. T., Canadian Journal of Chemistry, Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series, Organic Chemistry, General Chemistry, Catalysis |
| title | Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_full | Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_fullStr | Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_full_unstemmed | Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_short | Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_sort | thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| title_unstemmed | Thermal and photolytic decomposition reactions of diazo compounds in the bicyclo[4 •1•0]heptane series |
| topic | Organic Chemistry, General Chemistry, Catalysis |
| url | http://dx.doi.org/10.1139/v68-262 |