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Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data
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| Zeitschriftentitel: | Acta Crystallographica Section E Crystallographic Communications |
|---|---|
| Personen und Körperschaften: | , |
| In: | Acta Crystallographica Section E Crystallographic Communications, 75, 2019, 4, S. 428-431 |
| Format: | E-Article |
| Sprache: | Unbestimmt |
| veröffentlicht: |
International Union of Crystallography (IUCr)
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| Schlagwörter: |
| author_facet |
Moon, Dohyun Choi, Jong-Ha Moon, Dohyun Choi, Jong-Ha |
|---|---|
| author |
Moon, Dohyun Choi, Jong-Ha |
| spellingShingle |
Moon, Dohyun Choi, Jong-Ha Acta Crystallographica Section E Crystallographic Communications Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data Condensed Matter Physics General Materials Science General Chemistry |
| author_sort |
moon, dohyun |
| spelling |
Moon, Dohyun Choi, Jong-Ha 2056-9890 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s2056989019003086 <jats:p>The structure of the title compound, [Cr(tacn)<jats:sub>2</jats:sub>]<jats:sub>2</jats:sub>[ZnCl<jats:sub>4</jats:sub>]<jats:sub>3</jats:sub>·H<jats:sub>2</jats:sub>O (tacn is 1,4,7-triazacyclononane; C<jats:sub>6</jats:sub>H<jats:sub>15</jats:sub>N<jats:sub>3</jats:sub>), has been determined from synchrotron X-ray data. Each Cr<jats:sup>III</jats:sup>cation is coordinated by the six N atoms from the two tacn ligands, displaying a distorted octahedral geometry. Three distorted tetrahedral [ZnCl<jats:sub>4</jats:sub>]<jats:sup>2−</jats:sup>anions and one lattice water molecule lie outside this coordination sphere. The Cr—N bond lengths are in the range 2.0621 (11) to 2.0851 (12) Å, while the mean inner N—Cr—N bond angle is 82.51 (5)°. The crystal packing is stabilized by hydrogen-bonding interactions with the N—H groups of the tacn ligands and the water O—H groups acting as donors, and the O atoms of the water molecules and Cl atoms of the [ZnCl<jats:sub>4</jats:sub>]<jats:sup>2−</jats:sup>anions as acceptors. Overall these contacts lead to the formation of a three-dimensional network.</jats:p> Crystal structure of bis[bis(1,4,7-triazacyclononane-κ<sup>3</sup><i>N</i>,<i>N</i>′,<i>N</i>′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data Acta Crystallographica Section E Crystallographic Communications |
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10.1107/s2056989019003086 |
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Online Free |
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Physik |
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International Union of Crystallography (IUCr), 2019 |
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International Union of Crystallography (IUCr), 2019 |
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2056-9890 |
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2056-9890 |
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International Union of Crystallography (IUCr) (CrossRef) |
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2019 |
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International Union of Crystallography (IUCr) |
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ai |
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ai |
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Acta Crystallographica Section E Crystallographic Communications |
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49 |
| title |
Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_unstemmed |
Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_full |
Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_fullStr |
Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_full_unstemmed |
Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_short |
Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_sort |
crystal structure of bis[bis(1,4,7-triazacyclononane-κ<sup>3</sup><i>n</i>,<i>n</i>′,<i>n</i>′′)chromium(iii)] tris(tetrachloridozincate) monohydrate from synchrotron x-ray data |
| topic |
Condensed Matter Physics General Materials Science General Chemistry |
| url |
http://dx.doi.org/10.1107/s2056989019003086 |
| publishDate |
2019 |
| physical |
428-431 |
| description |
<jats:p>The structure of the title compound, [Cr(tacn)<jats:sub>2</jats:sub>]<jats:sub>2</jats:sub>[ZnCl<jats:sub>4</jats:sub>]<jats:sub>3</jats:sub>·H<jats:sub>2</jats:sub>O (tacn is 1,4,7-triazacyclononane; C<jats:sub>6</jats:sub>H<jats:sub>15</jats:sub>N<jats:sub>3</jats:sub>), has been determined from synchrotron X-ray data. Each Cr<jats:sup>III</jats:sup>cation is coordinated by the six N atoms from the two tacn ligands, displaying a distorted octahedral geometry. Three distorted tetrahedral [ZnCl<jats:sub>4</jats:sub>]<jats:sup>2−</jats:sup>anions and one lattice water molecule lie outside this coordination sphere. The Cr—N bond lengths are in the range 2.0621 (11) to 2.0851 (12) Å, while the mean inner N—Cr—N bond angle is 82.51 (5)°. The crystal packing is stabilized by hydrogen-bonding interactions with the N—H groups of the tacn ligands and the water O—H groups acting as donors, and the O atoms of the water molecules and Cl atoms of the [ZnCl<jats:sub>4</jats:sub>]<jats:sup>2−</jats:sup>anions as acceptors. Overall these contacts lead to the formation of a three-dimensional network.</jats:p> |
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| author | Moon, Dohyun, Choi, Jong-Ha |
| author_facet | Moon, Dohyun, Choi, Jong-Ha, Moon, Dohyun, Choi, Jong-Ha |
| author_sort | moon, dohyun |
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| container_start_page | 428 |
| container_title | Acta Crystallographica Section E Crystallographic Communications |
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| description | <jats:p>The structure of the title compound, [Cr(tacn)<jats:sub>2</jats:sub>]<jats:sub>2</jats:sub>[ZnCl<jats:sub>4</jats:sub>]<jats:sub>3</jats:sub>·H<jats:sub>2</jats:sub>O (tacn is 1,4,7-triazacyclononane; C<jats:sub>6</jats:sub>H<jats:sub>15</jats:sub>N<jats:sub>3</jats:sub>), has been determined from synchrotron X-ray data. Each Cr<jats:sup>III</jats:sup>cation is coordinated by the six N atoms from the two tacn ligands, displaying a distorted octahedral geometry. Three distorted tetrahedral [ZnCl<jats:sub>4</jats:sub>]<jats:sup>2−</jats:sup>anions and one lattice water molecule lie outside this coordination sphere. The Cr—N bond lengths are in the range 2.0621 (11) to 2.0851 (12) Å, while the mean inner N—Cr—N bond angle is 82.51 (5)°. The crystal packing is stabilized by hydrogen-bonding interactions with the N—H groups of the tacn ligands and the water O—H groups acting as donors, and the O atoms of the water molecules and Cl atoms of the [ZnCl<jats:sub>4</jats:sub>]<jats:sup>2−</jats:sup>anions as acceptors. Overall these contacts lead to the formation of a three-dimensional network.</jats:p> |
| doi_str_mv | 10.1107/s2056989019003086 |
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| imprint | International Union of Crystallography (IUCr), 2019 |
| imprint_str_mv | International Union of Crystallography (IUCr), 2019 |
| institution | DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Zwi2, DE-Gla1, DE-Zi4 |
| issn | 2056-9890 |
| issn_str_mv | 2056-9890 |
| language | Undetermined |
| last_indexed | 2024-03-01T18:04:53.254Z |
| match_str | moon2019crystalstructureofbisbis147triazacyclononanek3nnnchromiumiiitristetrachloridozincatemonohydratefromsynchrotronxraydata |
| mega_collection | International Union of Crystallography (IUCr) (CrossRef) |
| physical | 428-431 |
| publishDate | 2019 |
| publishDateSort | 2019 |
| publisher | International Union of Crystallography (IUCr) |
| record_format | ai |
| recordtype | ai |
| series | Acta Crystallographica Section E Crystallographic Communications |
| source_id | 49 |
| spelling | Moon, Dohyun Choi, Jong-Ha 2056-9890 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s2056989019003086 <jats:p>The structure of the title compound, [Cr(tacn)<jats:sub>2</jats:sub>]<jats:sub>2</jats:sub>[ZnCl<jats:sub>4</jats:sub>]<jats:sub>3</jats:sub>·H<jats:sub>2</jats:sub>O (tacn is 1,4,7-triazacyclononane; C<jats:sub>6</jats:sub>H<jats:sub>15</jats:sub>N<jats:sub>3</jats:sub>), has been determined from synchrotron X-ray data. Each Cr<jats:sup>III</jats:sup>cation is coordinated by the six N atoms from the two tacn ligands, displaying a distorted octahedral geometry. Three distorted tetrahedral [ZnCl<jats:sub>4</jats:sub>]<jats:sup>2−</jats:sup>anions and one lattice water molecule lie outside this coordination sphere. The Cr—N bond lengths are in the range 2.0621 (11) to 2.0851 (12) Å, while the mean inner N—Cr—N bond angle is 82.51 (5)°. The crystal packing is stabilized by hydrogen-bonding interactions with the N—H groups of the tacn ligands and the water O—H groups acting as donors, and the O atoms of the water molecules and Cl atoms of the [ZnCl<jats:sub>4</jats:sub>]<jats:sup>2−</jats:sup>anions as acceptors. Overall these contacts lead to the formation of a three-dimensional network.</jats:p> Crystal structure of bis[bis(1,4,7-triazacyclononane-κ<sup>3</sup><i>N</i>,<i>N</i>′,<i>N</i>′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data Acta Crystallographica Section E Crystallographic Communications |
| spellingShingle | Moon, Dohyun, Choi, Jong-Ha, Acta Crystallographica Section E Crystallographic Communications, Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data, Condensed Matter Physics, General Materials Science, General Chemistry |
| title | Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_full | Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_fullStr | Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_full_unstemmed | Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_short | Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| title_sort | crystal structure of bis[bis(1,4,7-triazacyclononane-κ<sup>3</sup><i>n</i>,<i>n</i>′,<i>n</i>′′)chromium(iii)] tris(tetrachloridozincate) monohydrate from synchrotron x-ray data |
| title_unstemmed | Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data |
| topic | Condensed Matter Physics, General Materials Science, General Chemistry |
| url | http://dx.doi.org/10.1107/s2056989019003086 |