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Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data
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| Zeitschriftentitel: | Acta Crystallographica Section E Crystallographic Communications |
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| Personen und Körperschaften: | , , |
| In: | Acta Crystallographica Section E Crystallographic Communications, 72, 2016, 9, S. 1293-1296 |
| Format: | E-Article |
| Sprache: | Unbestimmt |
| veröffentlicht: |
International Union of Crystallography (IUCr)
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| Schlagwörter: |
| author_facet |
Moon, Dohyun Ryoo, Keon Sang Choi, Jong-Ha Moon, Dohyun Ryoo, Keon Sang Choi, Jong-Ha |
|---|---|
| author |
Moon, Dohyun Ryoo, Keon Sang Choi, Jong-Ha |
| spellingShingle |
Moon, Dohyun Ryoo, Keon Sang Choi, Jong-Ha Acta Crystallographica Section E Crystallographic Communications Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data Condensed Matter Physics General Materials Science General Chemistry |
| author_sort |
moon, dohyun |
| spelling |
Moon, Dohyun Ryoo, Keon Sang Choi, Jong-Ha 2056-9890 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s2056989016012755 <jats:p>The structure of the title compound, [CrCl<jats:sub>2</jats:sub>(tn)<jats:sub>2</jats:sub>]<jats:sub>2</jats:sub>[Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>] (tn = propane-1,3-diamine; C<jats:sub>3</jats:sub>H<jats:sub>10</jats:sub>N<jats:sub>2</jats:sub>), has been determined from synchrotron data. The asymmetric unit contains one Cr<jats:sup>III</jats:sup>complex cation and half a [Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>]<jats:sup>2−</jats:sup>anion. In the complex cation, the Cr<jats:sup>III</jats:sup>ion is coordinated by the four N atoms of two propane-1,3-diamine (tn) ligands in the equatorial plane and by two Cl atoms in a<jats:italic>trans</jats:italic>configuration, displaying a distorted octahedral coordination sphere. The two six-membered rings in the complex cation have an<jats:italic>anti</jats:italic>chair–chair conformation with respect to each other. The mean Cr—N(tn) and Cr—Cl bond lengths are 2.09 (1) and 2.320 (2) Å, respectively. The slightly bent dichromate anion is disordered over two sets of sites (occupancy ratio = 0.7:0.3) and has a staggered conformation. The crystal structure is stabilized by intermolecular hydrogen bonds involving the NH<jats:sub>2</jats:sub>groups of the tn ligands as donors and the O atoms of the [Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>]<jats:sup>2−</jats:sup>anion and chlorido ligands as acceptors.</jats:p> Crystal structure of bis[<i>trans</i>-dichloridobis(propane-1,3-diamine-κ<sup>2</sup><i>N</i>,<i>N</i>′)chromium(III)] dichromate from synchrotron data Acta Crystallographica Section E Crystallographic Communications |
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10.1107/s2056989016012755 |
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Online Free |
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Physik |
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ElectronicArticle |
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DE-Pl11 DE-Rs1 DE-105 DE-14 DE-Ch1 DE-L229 DE-D275 DE-Bn3 DE-Brt1 DE-Zwi2 DE-D161 DE-Gla1 DE-Zi4 DE-15 |
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International Union of Crystallography (IUCr), 2016 |
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International Union of Crystallography (IUCr), 2016 |
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2056-9890 |
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2056-9890 |
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International Union of Crystallography (IUCr) (CrossRef) |
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moon2016crystalstructureofbistransdichloridobispropane13diaminek2nnchromiumiiidichromatefromsynchrotrondata |
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2016 |
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International Union of Crystallography (IUCr) |
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Acta Crystallographica Section E Crystallographic Communications |
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| title |
Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_unstemmed |
Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_full |
Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_fullStr |
Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_full_unstemmed |
Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_short |
Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_sort |
crystal structure of bis[<i>trans</i>-dichloridobis(propane-1,3-diamine-κ<sup>2</sup><i>n</i>,<i>n</i>′)chromium(iii)] dichromate from synchrotron data |
| topic |
Condensed Matter Physics General Materials Science General Chemistry |
| url |
http://dx.doi.org/10.1107/s2056989016012755 |
| publishDate |
2016 |
| physical |
1293-1296 |
| description |
<jats:p>The structure of the title compound, [CrCl<jats:sub>2</jats:sub>(tn)<jats:sub>2</jats:sub>]<jats:sub>2</jats:sub>[Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>] (tn = propane-1,3-diamine; C<jats:sub>3</jats:sub>H<jats:sub>10</jats:sub>N<jats:sub>2</jats:sub>), has been determined from synchrotron data. The asymmetric unit contains one Cr<jats:sup>III</jats:sup>complex cation and half a [Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>]<jats:sup>2−</jats:sup>anion. In the complex cation, the Cr<jats:sup>III</jats:sup>ion is coordinated by the four N atoms of two propane-1,3-diamine (tn) ligands in the equatorial plane and by two Cl atoms in a<jats:italic>trans</jats:italic>configuration, displaying a distorted octahedral coordination sphere. The two six-membered rings in the complex cation have an<jats:italic>anti</jats:italic>chair–chair conformation with respect to each other. The mean Cr—N(tn) and Cr—Cl bond lengths are 2.09 (1) and 2.320 (2) Å, respectively. The slightly bent dichromate anion is disordered over two sets of sites (occupancy ratio = 0.7:0.3) and has a staggered conformation. The crystal structure is stabilized by intermolecular hydrogen bonds involving the NH<jats:sub>2</jats:sub>groups of the tn ligands as donors and the O atoms of the [Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>]<jats:sup>2−</jats:sup>anion and chlorido ligands as acceptors.</jats:p> |
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| author | Moon, Dohyun, Ryoo, Keon Sang, Choi, Jong-Ha |
| author_facet | Moon, Dohyun, Ryoo, Keon Sang, Choi, Jong-Ha, Moon, Dohyun, Ryoo, Keon Sang, Choi, Jong-Ha |
| author_sort | moon, dohyun |
| container_issue | 9 |
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| description | <jats:p>The structure of the title compound, [CrCl<jats:sub>2</jats:sub>(tn)<jats:sub>2</jats:sub>]<jats:sub>2</jats:sub>[Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>] (tn = propane-1,3-diamine; C<jats:sub>3</jats:sub>H<jats:sub>10</jats:sub>N<jats:sub>2</jats:sub>), has been determined from synchrotron data. The asymmetric unit contains one Cr<jats:sup>III</jats:sup>complex cation and half a [Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>]<jats:sup>2−</jats:sup>anion. In the complex cation, the Cr<jats:sup>III</jats:sup>ion is coordinated by the four N atoms of two propane-1,3-diamine (tn) ligands in the equatorial plane and by two Cl atoms in a<jats:italic>trans</jats:italic>configuration, displaying a distorted octahedral coordination sphere. The two six-membered rings in the complex cation have an<jats:italic>anti</jats:italic>chair–chair conformation with respect to each other. The mean Cr—N(tn) and Cr—Cl bond lengths are 2.09 (1) and 2.320 (2) Å, respectively. The slightly bent dichromate anion is disordered over two sets of sites (occupancy ratio = 0.7:0.3) and has a staggered conformation. The crystal structure is stabilized by intermolecular hydrogen bonds involving the NH<jats:sub>2</jats:sub>groups of the tn ligands as donors and the O atoms of the [Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>]<jats:sup>2−</jats:sup>anion and chlorido ligands as acceptors.</jats:p> |
| doi_str_mv | 10.1107/s2056989016012755 |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTEwNy9zMjA1Njk4OTAxNjAxMjc1NQ |
| imprint | International Union of Crystallography (IUCr), 2016 |
| imprint_str_mv | International Union of Crystallography (IUCr), 2016 |
| institution | DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15 |
| issn | 2056-9890 |
| issn_str_mv | 2056-9890 |
| language | Undetermined |
| last_indexed | 2024-03-01T13:02:32.081Z |
| match_str | moon2016crystalstructureofbistransdichloridobispropane13diaminek2nnchromiumiiidichromatefromsynchrotrondata |
| mega_collection | International Union of Crystallography (IUCr) (CrossRef) |
| physical | 1293-1296 |
| publishDate | 2016 |
| publishDateSort | 2016 |
| publisher | International Union of Crystallography (IUCr) |
| record_format | ai |
| recordtype | ai |
| series | Acta Crystallographica Section E Crystallographic Communications |
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| spelling | Moon, Dohyun Ryoo, Keon Sang Choi, Jong-Ha 2056-9890 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s2056989016012755 <jats:p>The structure of the title compound, [CrCl<jats:sub>2</jats:sub>(tn)<jats:sub>2</jats:sub>]<jats:sub>2</jats:sub>[Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>] (tn = propane-1,3-diamine; C<jats:sub>3</jats:sub>H<jats:sub>10</jats:sub>N<jats:sub>2</jats:sub>), has been determined from synchrotron data. The asymmetric unit contains one Cr<jats:sup>III</jats:sup>complex cation and half a [Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>]<jats:sup>2−</jats:sup>anion. In the complex cation, the Cr<jats:sup>III</jats:sup>ion is coordinated by the four N atoms of two propane-1,3-diamine (tn) ligands in the equatorial plane and by two Cl atoms in a<jats:italic>trans</jats:italic>configuration, displaying a distorted octahedral coordination sphere. The two six-membered rings in the complex cation have an<jats:italic>anti</jats:italic>chair–chair conformation with respect to each other. The mean Cr—N(tn) and Cr—Cl bond lengths are 2.09 (1) and 2.320 (2) Å, respectively. The slightly bent dichromate anion is disordered over two sets of sites (occupancy ratio = 0.7:0.3) and has a staggered conformation. The crystal structure is stabilized by intermolecular hydrogen bonds involving the NH<jats:sub>2</jats:sub>groups of the tn ligands as donors and the O atoms of the [Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>]<jats:sup>2−</jats:sup>anion and chlorido ligands as acceptors.</jats:p> Crystal structure of bis[<i>trans</i>-dichloridobis(propane-1,3-diamine-κ<sup>2</sup><i>N</i>,<i>N</i>′)chromium(III)] dichromate from synchrotron data Acta Crystallographica Section E Crystallographic Communications |
| spellingShingle | Moon, Dohyun, Ryoo, Keon Sang, Choi, Jong-Ha, Acta Crystallographica Section E Crystallographic Communications, Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data, Condensed Matter Physics, General Materials Science, General Chemistry |
| title | Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_full | Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_fullStr | Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_full_unstemmed | Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_short | Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| title_sort | crystal structure of bis[<i>trans</i>-dichloridobis(propane-1,3-diamine-κ<sup>2</sup><i>n</i>,<i>n</i>′)chromium(iii)] dichromate from synchrotron data |
| title_unstemmed | Crystal structure of bis[trans-dichloridobis(propane-1,3-diamine-κ2N,N′)chromium(III)] dichromate from synchrotron data |
| topic | Condensed Matter Physics, General Materials Science, General Chemistry |
| url | http://dx.doi.org/10.1107/s2056989016012755 |