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Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data
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| Zeitschriftentitel: | Acta Crystallographica Section E Crystallographic Communications |
|---|---|
| Personen und Körperschaften: | , |
| In: | Acta Crystallographica Section E Crystallographic Communications, 72, 2016, 3, S. 424-427 |
| Format: | E-Article |
| Sprache: | Unbestimmt |
| veröffentlicht: |
International Union of Crystallography (IUCr)
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| Schlagwörter: |
| author_facet |
Moon, Dohyun Choi, Jong-Ha Moon, Dohyun Choi, Jong-Ha |
|---|---|
| author |
Moon, Dohyun Choi, Jong-Ha |
| spellingShingle |
Moon, Dohyun Choi, Jong-Ha Acta Crystallographica Section E Crystallographic Communications Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data Condensed Matter Physics General Materials Science General Chemistry |
| author_sort |
moon, dohyun |
| spelling |
Moon, Dohyun Choi, Jong-Ha 2056-9890 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s2056989016002978 <jats:p>The structure of the title complex, [CrCl<jats:sub>2</jats:sub>(2,3,2-tet)]ClO<jats:sub>4</jats:sub>(2,3,2-tet is 1,4,8,11-tetraazaundecane, C<jats:sub>7</jats:sub>H<jats:sub>20</jats:sub>N<jats:sub>4</jats:sub>), has been determined from synchrotron data. The Cr<jats:sup>III</jats:sup>ion is coordinated by the four N atoms of the 1,4,8,11-tetraazaundecane ligand in the equatorial plane and two chloride ions in an axial arrangement, displaying a slightly distorted octahedral coordination environment. The two H atoms of the secondary amines are grouped on the same side of the equatorial N<jats:sub>4</jats:sub>plane (<jats:italic>meso</jats:italic>-<jats:italic>RS</jats:italic>conformation). The Cr—N bond lengths range from 2.069 (2) to 2.084 (2) Å, while the mean Cr—Cl bond length is 2.325 (2) Å. The crystal structure is stabilized by intermolecular hydrogen-bonding interactions between the primary and secondary amine groups of the 2,3,2-tet ligands, the Cl ligands and the O atoms of the perchlorate counter-anion, forming corrugated layers parallel to (010).</jats:p> Crystal structure of<i>trans</i>-dichlorido(1,4,8,11-tetraazaundecane-κ<sup>4</sup><i>N</i>)chromium(III) perchlorate determined from synchrotron data Acta Crystallographica Section E Crystallographic Communications |
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10.1107/s2056989016002978 |
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Online Free |
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Physik |
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ElectronicArticle |
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International Union of Crystallography (IUCr), 2016 |
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International Union of Crystallography (IUCr), 2016 |
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2056-9890 |
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2056-9890 |
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International Union of Crystallography (IUCr) (CrossRef) |
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moon2016crystalstructureoftransdichlorido14811tetraazaundecanek4nchromiumiiiperchloratedeterminedfromsynchrotrondata |
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2016 |
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International Union of Crystallography (IUCr) |
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ai |
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ai |
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Acta Crystallographica Section E Crystallographic Communications |
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49 |
| title |
Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_unstemmed |
Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_full |
Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_fullStr |
Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_full_unstemmed |
Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_short |
Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_sort |
crystal structure of<i>trans</i>-dichlorido(1,4,8,11-tetraazaundecane-κ<sup>4</sup><i>n</i>)chromium(iii) perchlorate determined from synchrotron data |
| topic |
Condensed Matter Physics General Materials Science General Chemistry |
| url |
http://dx.doi.org/10.1107/s2056989016002978 |
| publishDate |
2016 |
| physical |
424-427 |
| description |
<jats:p>The structure of the title complex, [CrCl<jats:sub>2</jats:sub>(2,3,2-tet)]ClO<jats:sub>4</jats:sub>(2,3,2-tet is 1,4,8,11-tetraazaundecane, C<jats:sub>7</jats:sub>H<jats:sub>20</jats:sub>N<jats:sub>4</jats:sub>), has been determined from synchrotron data. The Cr<jats:sup>III</jats:sup>ion is coordinated by the four N atoms of the 1,4,8,11-tetraazaundecane ligand in the equatorial plane and two chloride ions in an axial arrangement, displaying a slightly distorted octahedral coordination environment. The two H atoms of the secondary amines are grouped on the same side of the equatorial N<jats:sub>4</jats:sub>plane (<jats:italic>meso</jats:italic>-<jats:italic>RS</jats:italic>conformation). The Cr—N bond lengths range from 2.069 (2) to 2.084 (2) Å, while the mean Cr—Cl bond length is 2.325 (2) Å. The crystal structure is stabilized by intermolecular hydrogen-bonding interactions between the primary and secondary amine groups of the 2,3,2-tet ligands, the Cl ligands and the O atoms of the perchlorate counter-anion, forming corrugated layers parallel to (010).</jats:p> |
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| _version_ | 1792329366486646787 |
| author | Moon, Dohyun, Choi, Jong-Ha |
| author_facet | Moon, Dohyun, Choi, Jong-Ha, Moon, Dohyun, Choi, Jong-Ha |
| author_sort | moon, dohyun |
| container_issue | 3 |
| container_start_page | 424 |
| container_title | Acta Crystallographica Section E Crystallographic Communications |
| container_volume | 72 |
| description | <jats:p>The structure of the title complex, [CrCl<jats:sub>2</jats:sub>(2,3,2-tet)]ClO<jats:sub>4</jats:sub>(2,3,2-tet is 1,4,8,11-tetraazaundecane, C<jats:sub>7</jats:sub>H<jats:sub>20</jats:sub>N<jats:sub>4</jats:sub>), has been determined from synchrotron data. The Cr<jats:sup>III</jats:sup>ion is coordinated by the four N atoms of the 1,4,8,11-tetraazaundecane ligand in the equatorial plane and two chloride ions in an axial arrangement, displaying a slightly distorted octahedral coordination environment. The two H atoms of the secondary amines are grouped on the same side of the equatorial N<jats:sub>4</jats:sub>plane (<jats:italic>meso</jats:italic>-<jats:italic>RS</jats:italic>conformation). The Cr—N bond lengths range from 2.069 (2) to 2.084 (2) Å, while the mean Cr—Cl bond length is 2.325 (2) Å. The crystal structure is stabilized by intermolecular hydrogen-bonding interactions between the primary and secondary amine groups of the 2,3,2-tet ligands, the Cl ligands and the O atoms of the perchlorate counter-anion, forming corrugated layers parallel to (010).</jats:p> |
| doi_str_mv | 10.1107/s2056989016002978 |
| facet_avail | Online, Free |
| finc_class_facet | Physik |
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| format_de15 | Article, E-Article |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTEwNy9zMjA1Njk4OTAxNjAwMjk3OA |
| imprint | International Union of Crystallography (IUCr), 2016 |
| imprint_str_mv | International Union of Crystallography (IUCr), 2016 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-D161, DE-Zwi2 |
| issn | 2056-9890 |
| issn_str_mv | 2056-9890 |
| language | Undetermined |
| last_indexed | 2024-03-01T13:08:00.77Z |
| match_str | moon2016crystalstructureoftransdichlorido14811tetraazaundecanek4nchromiumiiiperchloratedeterminedfromsynchrotrondata |
| mega_collection | International Union of Crystallography (IUCr) (CrossRef) |
| physical | 424-427 |
| publishDate | 2016 |
| publishDateSort | 2016 |
| publisher | International Union of Crystallography (IUCr) |
| record_format | ai |
| recordtype | ai |
| series | Acta Crystallographica Section E Crystallographic Communications |
| source_id | 49 |
| spelling | Moon, Dohyun Choi, Jong-Ha 2056-9890 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s2056989016002978 <jats:p>The structure of the title complex, [CrCl<jats:sub>2</jats:sub>(2,3,2-tet)]ClO<jats:sub>4</jats:sub>(2,3,2-tet is 1,4,8,11-tetraazaundecane, C<jats:sub>7</jats:sub>H<jats:sub>20</jats:sub>N<jats:sub>4</jats:sub>), has been determined from synchrotron data. The Cr<jats:sup>III</jats:sup>ion is coordinated by the four N atoms of the 1,4,8,11-tetraazaundecane ligand in the equatorial plane and two chloride ions in an axial arrangement, displaying a slightly distorted octahedral coordination environment. The two H atoms of the secondary amines are grouped on the same side of the equatorial N<jats:sub>4</jats:sub>plane (<jats:italic>meso</jats:italic>-<jats:italic>RS</jats:italic>conformation). The Cr—N bond lengths range from 2.069 (2) to 2.084 (2) Å, while the mean Cr—Cl bond length is 2.325 (2) Å. The crystal structure is stabilized by intermolecular hydrogen-bonding interactions between the primary and secondary amine groups of the 2,3,2-tet ligands, the Cl ligands and the O atoms of the perchlorate counter-anion, forming corrugated layers parallel to (010).</jats:p> Crystal structure of<i>trans</i>-dichlorido(1,4,8,11-tetraazaundecane-κ<sup>4</sup><i>N</i>)chromium(III) perchlorate determined from synchrotron data Acta Crystallographica Section E Crystallographic Communications |
| spellingShingle | Moon, Dohyun, Choi, Jong-Ha, Acta Crystallographica Section E Crystallographic Communications, Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data, Condensed Matter Physics, General Materials Science, General Chemistry |
| title | Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_full | Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_fullStr | Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_full_unstemmed | Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_short | Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| title_sort | crystal structure of<i>trans</i>-dichlorido(1,4,8,11-tetraazaundecane-κ<sup>4</sup><i>n</i>)chromium(iii) perchlorate determined from synchrotron data |
| title_unstemmed | Crystal structure oftrans-dichlorido(1,4,8,11-tetraazaundecane-κ4N)chromium(III) perchlorate determined from synchrotron data |
| topic | Condensed Matter Physics, General Materials Science, General Chemistry |
| url | http://dx.doi.org/10.1107/s2056989016002978 |