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Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data
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| Zeitschriftentitel: | Acta Crystallographica Section E Crystallographic Communications |
|---|---|
| Personen und Körperschaften: | , , , |
| In: | Acta Crystallographica Section E Crystallographic Communications, 71, 2015, 11, S. 1336-1339 |
| Format: | E-Article |
| Sprache: | Unbestimmt |
| veröffentlicht: |
International Union of Crystallography (IUCr)
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| Schlagwörter: |
| author_facet |
Moon, Dohyun Tanaka, Shinnosuke Akitsu, Takashiro Choi, Jong-Ha Moon, Dohyun Tanaka, Shinnosuke Akitsu, Takashiro Choi, Jong-Ha |
|---|---|
| author |
Moon, Dohyun Tanaka, Shinnosuke Akitsu, Takashiro Choi, Jong-Ha |
| spellingShingle |
Moon, Dohyun Tanaka, Shinnosuke Akitsu, Takashiro Choi, Jong-Ha Acta Crystallographica Section E Crystallographic Communications Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data Condensed Matter Physics General Materials Science General Chemistry |
| author_sort |
moon, dohyun |
| spelling |
Moon, Dohyun Tanaka, Shinnosuke Akitsu, Takashiro Choi, Jong-Ha 2056-9890 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s2056989015019258 <jats:p>The title bromide salt, [Cr{CO(NH<jats:sub>2</jats:sub>)<jats:sub>2</jats:sub>}<jats:sub>6</jats:sub>](Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>)Br·H<jats:sub>2</jats:sub>O, is isotypic to the corresponding chloride salt. Within the complex cation, the Cr<jats:sup>III</jats:sup>atom is coordinated by six O atoms of six urea ligands, displaying a slightly distorted octahedral coordination environment. The Cr—O bond lengths involving the urea ligands are in the range 1.9534 (13)–1.9776 (12) Å. The Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub><jats:sup>2−</jats:sup>anion has a nearly staggered conformation, with a bridging angle of 130.26 (10)°. The individual components are arranged in rows extending parallel to [100]. The Br<jats:sup>−</jats:sup>anion links the complex cation, as well as the solvent water molecule, through N—H...Br and O—H...Br hydrogen-bonding interactions. The supramolecular architecture also includes N—H...O and O—H...O hydrogen bonding between urea N—H and water O—H donor groups and the O atoms of the Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub><jats:sup>2−</jats:sup>anion as acceptor atoms, leading to a three-dimensional network structure.</jats:p> Crystal structure of hexakis(urea-κ<i>O</i>)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data Acta Crystallographica Section E Crystallographic Communications |
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10.1107/s2056989015019258 |
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Physik |
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ElectronicArticle |
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International Union of Crystallography (IUCr), 2015 |
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International Union of Crystallography (IUCr), 2015 |
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2056-9890 |
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Acta Crystallographica Section E Crystallographic Communications |
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| title |
Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_unstemmed |
Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_full |
Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_fullStr |
Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_full_unstemmed |
Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_short |
Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_sort |
crystal structure of hexakis(urea-κ<i>o</i>)chromium(iii) dichromate bromide monohydrate from synchrotron x-ray data |
| topic |
Condensed Matter Physics General Materials Science General Chemistry |
| url |
http://dx.doi.org/10.1107/s2056989015019258 |
| publishDate |
2015 |
| physical |
1336-1339 |
| description |
<jats:p>The title bromide salt, [Cr{CO(NH<jats:sub>2</jats:sub>)<jats:sub>2</jats:sub>}<jats:sub>6</jats:sub>](Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>)Br·H<jats:sub>2</jats:sub>O, is isotypic to the corresponding chloride salt. Within the complex cation, the Cr<jats:sup>III</jats:sup>atom is coordinated by six O atoms of six urea ligands, displaying a slightly distorted octahedral coordination environment. The Cr—O bond lengths involving the urea ligands are in the range 1.9534 (13)–1.9776 (12) Å. The Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub><jats:sup>2−</jats:sup>anion has a nearly staggered conformation, with a bridging angle of 130.26 (10)°. The individual components are arranged in rows extending parallel to [100]. The Br<jats:sup>−</jats:sup>anion links the complex cation, as well as the solvent water molecule, through N—H...Br and O—H...Br hydrogen-bonding interactions. The supramolecular architecture also includes N—H...O and O—H...O hydrogen bonding between urea N—H and water O—H donor groups and the O atoms of the Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub><jats:sup>2−</jats:sup>anion as acceptor atoms, leading to a three-dimensional network structure.</jats:p> |
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| author | Moon, Dohyun, Tanaka, Shinnosuke, Akitsu, Takashiro, Choi, Jong-Ha |
| author_facet | Moon, Dohyun, Tanaka, Shinnosuke, Akitsu, Takashiro, Choi, Jong-Ha, Moon, Dohyun, Tanaka, Shinnosuke, Akitsu, Takashiro, Choi, Jong-Ha |
| author_sort | moon, dohyun |
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| description | <jats:p>The title bromide salt, [Cr{CO(NH<jats:sub>2</jats:sub>)<jats:sub>2</jats:sub>}<jats:sub>6</jats:sub>](Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>)Br·H<jats:sub>2</jats:sub>O, is isotypic to the corresponding chloride salt. Within the complex cation, the Cr<jats:sup>III</jats:sup>atom is coordinated by six O atoms of six urea ligands, displaying a slightly distorted octahedral coordination environment. The Cr—O bond lengths involving the urea ligands are in the range 1.9534 (13)–1.9776 (12) Å. The Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub><jats:sup>2−</jats:sup>anion has a nearly staggered conformation, with a bridging angle of 130.26 (10)°. The individual components are arranged in rows extending parallel to [100]. The Br<jats:sup>−</jats:sup>anion links the complex cation, as well as the solvent water molecule, through N—H...Br and O—H...Br hydrogen-bonding interactions. The supramolecular architecture also includes N—H...O and O—H...O hydrogen bonding between urea N—H and water O—H donor groups and the O atoms of the Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub><jats:sup>2−</jats:sup>anion as acceptor atoms, leading to a three-dimensional network structure.</jats:p> |
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| imprint | International Union of Crystallography (IUCr), 2015 |
| imprint_str_mv | International Union of Crystallography (IUCr), 2015 |
| institution | DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161 |
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| issn_str_mv | 2056-9890 |
| language | Undetermined |
| last_indexed | 2024-03-01T14:23:02.709Z |
| match_str | moon2015crystalstructureofhexakisureakochromiumiiidichromatebromidemonohydratefromsynchrotronxraydata |
| mega_collection | International Union of Crystallography (IUCr) (CrossRef) |
| physical | 1336-1339 |
| publishDate | 2015 |
| publishDateSort | 2015 |
| publisher | International Union of Crystallography (IUCr) |
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| series | Acta Crystallographica Section E Crystallographic Communications |
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| spelling | Moon, Dohyun Tanaka, Shinnosuke Akitsu, Takashiro Choi, Jong-Ha 2056-9890 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s2056989015019258 <jats:p>The title bromide salt, [Cr{CO(NH<jats:sub>2</jats:sub>)<jats:sub>2</jats:sub>}<jats:sub>6</jats:sub>](Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>)Br·H<jats:sub>2</jats:sub>O, is isotypic to the corresponding chloride salt. Within the complex cation, the Cr<jats:sup>III</jats:sup>atom is coordinated by six O atoms of six urea ligands, displaying a slightly distorted octahedral coordination environment. The Cr—O bond lengths involving the urea ligands are in the range 1.9534 (13)–1.9776 (12) Å. The Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub><jats:sup>2−</jats:sup>anion has a nearly staggered conformation, with a bridging angle of 130.26 (10)°. The individual components are arranged in rows extending parallel to [100]. The Br<jats:sup>−</jats:sup>anion links the complex cation, as well as the solvent water molecule, through N—H...Br and O—H...Br hydrogen-bonding interactions. The supramolecular architecture also includes N—H...O and O—H...O hydrogen bonding between urea N—H and water O—H donor groups and the O atoms of the Cr<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub><jats:sup>2−</jats:sup>anion as acceptor atoms, leading to a three-dimensional network structure.</jats:p> Crystal structure of hexakis(urea-κ<i>O</i>)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data Acta Crystallographica Section E Crystallographic Communications |
| spellingShingle | Moon, Dohyun, Tanaka, Shinnosuke, Akitsu, Takashiro, Choi, Jong-Ha, Acta Crystallographica Section E Crystallographic Communications, Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data, Condensed Matter Physics, General Materials Science, General Chemistry |
| title | Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_full | Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_fullStr | Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_full_unstemmed | Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_short | Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| title_sort | crystal structure of hexakis(urea-κ<i>o</i>)chromium(iii) dichromate bromide monohydrate from synchrotron x-ray data |
| title_unstemmed | Crystal structure of hexakis(urea-κO)chromium(III) dichromate bromide monohydrate from synchrotron X-ray data |
| topic | Condensed Matter Physics, General Materials Science, General Chemistry |
| url | http://dx.doi.org/10.1107/s2056989015019258 |