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(4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate
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| Zeitschriftentitel: | Acta Crystallographica Section E Structure Reports Online |
|---|---|
| Personen und Körperschaften: | , , , , |
| In: | Acta Crystallographica Section E Structure Reports Online, 70, 2014, 8, S. o866-o867 |
| Format: | E-Article |
| Sprache: | Unbestimmt |
| veröffentlicht: |
International Union of Crystallography (IUCr)
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| Schlagwörter: |
| author_facet |
Oubabi, Radouane Auhmani, Aziz Ait Itto, My Youssef Auhmani, Abdelwahed Daran, Jean-Claude Oubabi, Radouane Auhmani, Aziz Ait Itto, My Youssef Auhmani, Abdelwahed Daran, Jean-Claude |
|---|---|
| author |
Oubabi, Radouane Auhmani, Aziz Ait Itto, My Youssef Auhmani, Abdelwahed Daran, Jean-Claude |
| spellingShingle |
Oubabi, Radouane Auhmani, Aziz Ait Itto, My Youssef Auhmani, Abdelwahed Daran, Jean-Claude Acta Crystallographica Section E Structure Reports Online (4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate Condensed Matter Physics General Materials Science General Chemistry |
| author_sort |
oubabi, radouane |
| spelling |
Oubabi, Radouane Auhmani, Aziz Ait Itto, My Youssef Auhmani, Abdelwahed Daran, Jean-Claude 1600-5368 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s1600536814015827 <jats:p>The title compound, C<jats:sub>27</jats:sub>H<jats:sub>34</jats:sub>O<jats:sub>2</jats:sub>, was hemisynthesized through direct benzoylation of the naturally occurring meroterpene totarol. The central fused six-membered ring has a half-chair conformation, whereas the terminal six-membered ring displays a chair conformation. The dihedral angle between the fused benzene ring and the benzoyl benzene ring is 73.05 (14)°. The<jats:italic>S</jats:italic>,<jats:italic>S</jats:italic>chirality of the molecule is consistent with the synthetic pathway, and confirmed by the refinement of the Flack parameter.</jats:p> (4b<i>S</i>,8a<i>S</i>)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate Acta Crystallographica Section E Structure Reports Online |
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10.1107/s1600536814015827 |
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Online Free |
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Physik |
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International Union of Crystallography (IUCr), 2014 |
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International Union of Crystallography (IUCr), 2014 |
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| title |
(4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_unstemmed |
(4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_full |
(4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_fullStr |
(4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_full_unstemmed |
(4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_short |
(4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_sort |
(4b<i>s</i>,8a<i>s</i>)-1-isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| topic |
Condensed Matter Physics General Materials Science General Chemistry |
| url |
http://dx.doi.org/10.1107/s1600536814015827 |
| publishDate |
2014 |
| physical |
o866-o867 |
| description |
<jats:p>The title compound, C<jats:sub>27</jats:sub>H<jats:sub>34</jats:sub>O<jats:sub>2</jats:sub>, was hemisynthesized through direct benzoylation of the naturally occurring meroterpene totarol. The central fused six-membered ring has a half-chair conformation, whereas the terminal six-membered ring displays a chair conformation. The dihedral angle between the fused benzene ring and the benzoyl benzene ring is 73.05 (14)°. The<jats:italic>S</jats:italic>,<jats:italic>S</jats:italic>chirality of the molecule is consistent with the synthetic pathway, and confirmed by the refinement of the Flack parameter.</jats:p> |
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| author | Oubabi, Radouane, Auhmani, Aziz, Ait Itto, My Youssef, Auhmani, Abdelwahed, Daran, Jean-Claude |
| author_facet | Oubabi, Radouane, Auhmani, Aziz, Ait Itto, My Youssef, Auhmani, Abdelwahed, Daran, Jean-Claude, Oubabi, Radouane, Auhmani, Aziz, Ait Itto, My Youssef, Auhmani, Abdelwahed, Daran, Jean-Claude |
| author_sort | oubabi, radouane |
| container_issue | 8 |
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| container_title | Acta Crystallographica Section E Structure Reports Online |
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| description | <jats:p>The title compound, C<jats:sub>27</jats:sub>H<jats:sub>34</jats:sub>O<jats:sub>2</jats:sub>, was hemisynthesized through direct benzoylation of the naturally occurring meroterpene totarol. The central fused six-membered ring has a half-chair conformation, whereas the terminal six-membered ring displays a chair conformation. The dihedral angle between the fused benzene ring and the benzoyl benzene ring is 73.05 (14)°. The<jats:italic>S</jats:italic>,<jats:italic>S</jats:italic>chirality of the molecule is consistent with the synthetic pathway, and confirmed by the refinement of the Flack parameter.</jats:p> |
| doi_str_mv | 10.1107/s1600536814015827 |
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| imprint | International Union of Crystallography (IUCr), 2014 |
| imprint_str_mv | International Union of Crystallography (IUCr), 2014 |
| institution | DE-105, DE-14, DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1 |
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| physical | o866-o867 |
| publishDate | 2014 |
| publishDateSort | 2014 |
| publisher | International Union of Crystallography (IUCr) |
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| series | Acta Crystallographica Section E Structure Reports Online |
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| spelling | Oubabi, Radouane Auhmani, Aziz Ait Itto, My Youssef Auhmani, Abdelwahed Daran, Jean-Claude 1600-5368 International Union of Crystallography (IUCr) Condensed Matter Physics General Materials Science General Chemistry http://dx.doi.org/10.1107/s1600536814015827 <jats:p>The title compound, C<jats:sub>27</jats:sub>H<jats:sub>34</jats:sub>O<jats:sub>2</jats:sub>, was hemisynthesized through direct benzoylation of the naturally occurring meroterpene totarol. The central fused six-membered ring has a half-chair conformation, whereas the terminal six-membered ring displays a chair conformation. The dihedral angle between the fused benzene ring and the benzoyl benzene ring is 73.05 (14)°. The<jats:italic>S</jats:italic>,<jats:italic>S</jats:italic>chirality of the molecule is consistent with the synthetic pathway, and confirmed by the refinement of the Flack parameter.</jats:p> (4b<i>S</i>,8a<i>S</i>)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate Acta Crystallographica Section E Structure Reports Online |
| spellingShingle | Oubabi, Radouane, Auhmani, Aziz, Ait Itto, My Youssef, Auhmani, Abdelwahed, Daran, Jean-Claude, Acta Crystallographica Section E Structure Reports Online, (4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate, Condensed Matter Physics, General Materials Science, General Chemistry |
| title | (4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_full | (4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_fullStr | (4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_full_unstemmed | (4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_short | (4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_sort | (4b<i>s</i>,8a<i>s</i>)-1-isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| title_unstemmed | (4bS,8aS)-1-Isopropyl-4b,8,8-trimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthren-2-yl benzoate |
| topic | Condensed Matter Physics, General Materials Science, General Chemistry |
| url | http://dx.doi.org/10.1107/s1600536814015827 |