Crystal structure of 2-amino-5-methylsulfanyl-1,3,4-thiadiazol-3-ium chloride monohydrate

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Bibliographische Detailangaben
Zeitschriftentitel:	Acta Crystallographica Section E Structure Reports Online
Personen und Körperschaften:	Soudani, Sarra, Aubert, Emmanuel, Jelsch, Christian, Ben Nasr, Cherif
In:	Acta Crystallographica Section E Structure Reports Online, 70, 2014, 9, S. o913-o914
Format:	E-Article
Sprache:	Unbestimmt
veröffentlicht:	International Union of Crystallography (IUCr)
Schlagwörter:	Condensed Matter Physics General Materials Science General Chemistry

Details
Zusammenfassung:	<jats:p>The title salt, C<jats:sub>3</jats:sub>H<jats:sub>6</jats:sub>N<jats:sub>3</jats:sub>S<jats:sub>2</jats:sub><jats:sup>+</jats:sup>·Cl<jats:sup>−</jats:sup>·H<jats:sub>2</jats:sub>O, crystallized with two organic cations, two chloride anions and two water molecules in the asymmetric unit. The methyl C atoms deviate from their respective bound ring planes by 0.081 and 0.002 Å. In the crystal, the components are connected<jats:italic>via</jats:italic>N—H...O, N—H...Cl and O—H...Cl hydrogen bonds, forming sheets lying parallel to (100). The sheets are linked into bilayers by O—H...Cl hydrogen bonds involving the chloride ions and water molecules. Within the bilayers there are π–π interactions [inter-centroid distances = 3.4654 (4) and 3.4789 (4) Å] involving inversion-related cations.</jats:p>
Umfang:	o913-o914
ISSN:	1600-5368
DOI:	10.1107/s1600536814015864