author_facet Librovich, Bronislav V.
Nowakowski, Andrzej F.
Chaer, Issa
Tassou, Savvas
Librovich, Bronislav V.
Nowakowski, Andrzej F.
Chaer, Issa
Tassou, Savvas
author Librovich, Bronislav V.
Nowakowski, Andrzej F.
Chaer, Issa
Tassou, Savvas
spellingShingle Librovich, Bronislav V.
Nowakowski, Andrzej F.
Chaer, Issa
Tassou, Savvas
PAMM
Non‐equilibrium gas‐liquid transition model
General Medicine
author_sort librovich, bronislav v.
spelling Librovich, Bronislav V. Nowakowski, Andrzej F. Chaer, Issa Tassou, Savvas 1617-7061 1617-7061 Wiley General Medicine http://dx.doi.org/10.1002/pamm.200700233 <jats:title>Abstract</jats:title><jats:p>A new rigorous mathematical model for evaporation/condensation, including boiling, has been proposed. A problem of phase transition and in particular evaporation/condensation is one of the most acute problems of modern technology with numerous applications in industry, such as: in refrigeration, distillation in chemical industry. It is very common to use equilibrium evaporation model, which assumes that concentrations of species in the gas phase is always at saturated condition. Such kind of approach can lead to significant errors, resulting in negative concentrations in complex computer simulations. In this work two analytical solution of simplified differential‐algebraic system have been obtained. One of them was deduced using assumption that the process is isothermal and gas volume fraction is constant. In the second solution the assumption about gas volume fraction has been removed. The code for numerical solution of differential‐algebraic system, using conservative scheme, has been developed. It was designed to solve both systems of equations with boiling and without. Numerical calculations of ammonia‐water system with various initial conditions, which correspond to evaporation and/or condensation of both components, have been performed. It has been shown that, although system quickly evolves to quasi equilibrium state (the differences between current and equilibrium concentrations are small) it is necessary to use non‐equilibrium evaporation model, to calculate accurately evaporation/condensation rates, and consequently all other dependent variables. (© 2008 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim)</jats:p> Non‐equilibrium gas‐liquid transition model PAMM
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title Non‐equilibrium gas‐liquid transition model
title_unstemmed Non‐equilibrium gas‐liquid transition model
title_full Non‐equilibrium gas‐liquid transition model
title_fullStr Non‐equilibrium gas‐liquid transition model
title_full_unstemmed Non‐equilibrium gas‐liquid transition model
title_short Non‐equilibrium gas‐liquid transition model
title_sort non‐equilibrium gas‐liquid transition model
topic General Medicine
url http://dx.doi.org/10.1002/pamm.200700233
publishDate 2007
physical 2100029-2100030
description <jats:title>Abstract</jats:title><jats:p>A new rigorous mathematical model for evaporation/condensation, including boiling, has been proposed. A problem of phase transition and in particular evaporation/condensation is one of the most acute problems of modern technology with numerous applications in industry, such as: in refrigeration, distillation in chemical industry. It is very common to use equilibrium evaporation model, which assumes that concentrations of species in the gas phase is always at saturated condition. Such kind of approach can lead to significant errors, resulting in negative concentrations in complex computer simulations. In this work two analytical solution of simplified differential‐algebraic system have been obtained. One of them was deduced using assumption that the process is isothermal and gas volume fraction is constant. In the second solution the assumption about gas volume fraction has been removed. The code for numerical solution of differential‐algebraic system, using conservative scheme, has been developed. It was designed to solve both systems of equations with boiling and without. Numerical calculations of ammonia‐water system with various initial conditions, which correspond to evaporation and/or condensation of both components, have been performed. It has been shown that, although system quickly evolves to quasi equilibrium state (the differences between current and equilibrium concentrations are small) it is necessary to use non‐equilibrium evaporation model, to calculate accurately evaporation/condensation rates, and consequently all other dependent variables. (© 2008 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim)</jats:p>
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author Librovich, Bronislav V., Nowakowski, Andrzej F., Chaer, Issa, Tassou, Savvas
author_facet Librovich, Bronislav V., Nowakowski, Andrzej F., Chaer, Issa, Tassou, Savvas, Librovich, Bronislav V., Nowakowski, Andrzej F., Chaer, Issa, Tassou, Savvas
author_sort librovich, bronislav v.
container_issue 1
container_start_page 2100029
container_title PAMM
container_volume 7
description <jats:title>Abstract</jats:title><jats:p>A new rigorous mathematical model for evaporation/condensation, including boiling, has been proposed. A problem of phase transition and in particular evaporation/condensation is one of the most acute problems of modern technology with numerous applications in industry, such as: in refrigeration, distillation in chemical industry. It is very common to use equilibrium evaporation model, which assumes that concentrations of species in the gas phase is always at saturated condition. Such kind of approach can lead to significant errors, resulting in negative concentrations in complex computer simulations. In this work two analytical solution of simplified differential‐algebraic system have been obtained. One of them was deduced using assumption that the process is isothermal and gas volume fraction is constant. In the second solution the assumption about gas volume fraction has been removed. The code for numerical solution of differential‐algebraic system, using conservative scheme, has been developed. It was designed to solve both systems of equations with boiling and without. Numerical calculations of ammonia‐water system with various initial conditions, which correspond to evaporation and/or condensation of both components, have been performed. It has been shown that, although system quickly evolves to quasi equilibrium state (the differences between current and equilibrium concentrations are small) it is necessary to use non‐equilibrium evaporation model, to calculate accurately evaporation/condensation rates, and consequently all other dependent variables. (© 2008 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim)</jats:p>
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spelling Librovich, Bronislav V. Nowakowski, Andrzej F. Chaer, Issa Tassou, Savvas 1617-7061 1617-7061 Wiley General Medicine http://dx.doi.org/10.1002/pamm.200700233 <jats:title>Abstract</jats:title><jats:p>A new rigorous mathematical model for evaporation/condensation, including boiling, has been proposed. A problem of phase transition and in particular evaporation/condensation is one of the most acute problems of modern technology with numerous applications in industry, such as: in refrigeration, distillation in chemical industry. It is very common to use equilibrium evaporation model, which assumes that concentrations of species in the gas phase is always at saturated condition. Such kind of approach can lead to significant errors, resulting in negative concentrations in complex computer simulations. In this work two analytical solution of simplified differential‐algebraic system have been obtained. One of them was deduced using assumption that the process is isothermal and gas volume fraction is constant. In the second solution the assumption about gas volume fraction has been removed. The code for numerical solution of differential‐algebraic system, using conservative scheme, has been developed. It was designed to solve both systems of equations with boiling and without. Numerical calculations of ammonia‐water system with various initial conditions, which correspond to evaporation and/or condensation of both components, have been performed. It has been shown that, although system quickly evolves to quasi equilibrium state (the differences between current and equilibrium concentrations are small) it is necessary to use non‐equilibrium evaporation model, to calculate accurately evaporation/condensation rates, and consequently all other dependent variables. (© 2008 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim)</jats:p> Non‐equilibrium gas‐liquid transition model PAMM
spellingShingle Librovich, Bronislav V., Nowakowski, Andrzej F., Chaer, Issa, Tassou, Savvas, PAMM, Non‐equilibrium gas‐liquid transition model, General Medicine
title Non‐equilibrium gas‐liquid transition model
title_full Non‐equilibrium gas‐liquid transition model
title_fullStr Non‐equilibrium gas‐liquid transition model
title_full_unstemmed Non‐equilibrium gas‐liquid transition model
title_short Non‐equilibrium gas‐liquid transition model
title_sort non‐equilibrium gas‐liquid transition model
title_unstemmed Non‐equilibrium gas‐liquid transition model
topic General Medicine
url http://dx.doi.org/10.1002/pamm.200700233