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Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation
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Veröffentlicht in: | Scientific reports Bd. 5.2015, Art.-Nr. 09984, insges. 11 Seiten |
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Personen und Körperschaften: | , , , , , , , , |
Titel: | Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation/ Sebastian Behr, Ulla Vainio, Martin Müller, Andreas Schreyer & Gerold A. Schneider |
Format: | E-Book-Kapitel |
Sprache: | Englisch |
veröffentlicht: |
2015
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Gesamtaufnahme: |
: Scientific reports, Bd. 5.2015, Art.-Nr. 09984, insges. 11 Seiten
, volume:5 |
Schlagwörter: | |
Quelle: | Verbunddaten SWB Lizenzfreie Online-Ressourcen |
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author | Behr, Sebastian, Vainio, Ulla, Müller, Martin, Schreyer, Andreas, Schneider, Gerold A. |
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contents | Parallel and concentric alignment of microscopic building blocks into several orders of magnitude larger structures is commonly observed in nature. However, if similarly aligned structures are artificially produced their thickness is generally limited to just about one or two orders of magnitude more than the dimensions of the smallest element. We show that sedimentation provides a promising approach to manufacture solid materials consisting of well-aligned platelet-shaped particles while being more than 30 000 times thicker than the individual particle. Such sediments contain up to 28 vol% of particles without any further treatment and can be densified to 67 vol% particle fraction by subsequent unidirectional pressing. The degree of orientation of the platelet-shaped particles within the sediments was tracked by high-energy X-ray diffraction measurements. The Hermans orientation parameter, a statistical measure of the quality of alignment, was determined to be 0.63 ± 0.03 already for as-sedimented samples while the standard deviation of the orientation distribution of particles, another measure of average misalignment, was found to be (21.5 ± 1.4)°. After pressing, these values further improved to (0.81 ± 0.01) and (14.6 ± 0.4)°, respectively. Such quality of alignment competes with, if not even exceeds, values reported in the literature. |
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spelling | Behr, Sebastian VerfasserIn (DE-588)119927075X (DE-627)168155562X aut, Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation Sebastian Behr, Ulla Vainio, Martin Müller, Andreas Schreyer & Gerold A. Schneider, 2015, Illustrationen, Diagramme, Text txt rdacontent, Computermedien c rdamedia, Online-Ressource cr rdacarrier, Parallel and concentric alignment of microscopic building blocks into several orders of magnitude larger structures is commonly observed in nature. However, if similarly aligned structures are artificially produced their thickness is generally limited to just about one or two orders of magnitude more than the dimensions of the smallest element. We show that sedimentation provides a promising approach to manufacture solid materials consisting of well-aligned platelet-shaped particles while being more than 30 000 times thicker than the individual particle. Such sediments contain up to 28 vol% of particles without any further treatment and can be densified to 67 vol% particle fraction by subsequent unidirectional pressing. The degree of orientation of the platelet-shaped particles within the sediments was tracked by high-energy X-ray diffraction measurements. The Hermans orientation parameter, a statistical measure of the quality of alignment, was determined to be 0.63 ± 0.03 already for as-sedimented samples while the standard deviation of the orientation distribution of particles, another measure of average misalignment, was found to be (21.5 ± 1.4)°. After pressing, these values further improved to (0.81 ± 0.01) and (14.6 ± 0.4)°, respectively. Such quality of alignment competes with, if not even exceeds, values reported in the literature., Bioinspired materials, Characterization and analytical techniques, Design, synthesis and processing, Self-assembly, Vainio, Ulla VerfasserIn aut, Müller, Martin VerfasserIn aut, Schreyer, Andreas 1963- VerfasserIn (DE-588)1015467431 (DE-627)705390527 (DE-576)350661618 aut, Schneider, Gerold A. VerfasserIn (DE-588)113530839X (DE-627)890264732 (DE-576)48976018X aut, Technische Universität Hamburg-Harburg Institut für Keramische Hochleistungswerkstoffe Sonstige Körperschaft (DE-588)10194308-8 (DE-627)558136303 (DE-576)277242886 oth, Institut für Werkstoffforschung Geesthacht Sonstige Körperschaft (DE-588)2129140-8 (DE-627)124360149 (DE-576)194415554 oth, Technische Universität Hamburg-Harburg Sonstige Körperschaft (DE-588)2067664-5 (DE-627)103632417 (DE-576)192125400 oth, SFB 986 Maßgeschneiderte Multiskalige Materialsysteme M3 Sonstige Körperschaft (DE-588)115661807X (DE-627)1019408316 (DE-576)502290641 oth, Enthalten in Scientific reports [London] : Macmillan Publishers Limited, part of Springer Nature, 2011 Bd. 5.2015, Art.-Nr. 09984, insges. 11 Seiten Online-Ressource (DE-627)663366712 (DE-600)2615211-3 (DE-576)346641179 2045-2322 nnns, volume:5 year:2015, https://doi.org/10.1038%2Fsrep09984 Resolving-System Volltext, http://nbn-resolving.de/urn:nbn:de:gbv:830-88216427 Resolving-System kostenfrei Volltext, https://doi.org/10.15480/882.1399 Resolving-System kostenfrei Volltext, http://hdl.handle.net/11420/1402 Resolving-System kostenfrei Volltext, http://nbn-resolving.de/urn:nbn:de:gbv:830-88216427 LFER, LFER 2019-07-22T00:00:00Z |
spellingShingle | Behr, Sebastian, Vainio, Ulla, Müller, Martin, Schreyer, Andreas, Schneider, Gerold A., Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation, Parallel and concentric alignment of microscopic building blocks into several orders of magnitude larger structures is commonly observed in nature. However, if similarly aligned structures are artificially produced their thickness is generally limited to just about one or two orders of magnitude more than the dimensions of the smallest element. We show that sedimentation provides a promising approach to manufacture solid materials consisting of well-aligned platelet-shaped particles while being more than 30 000 times thicker than the individual particle. Such sediments contain up to 28 vol% of particles without any further treatment and can be densified to 67 vol% particle fraction by subsequent unidirectional pressing. The degree of orientation of the platelet-shaped particles within the sediments was tracked by high-energy X-ray diffraction measurements. The Hermans orientation parameter, a statistical measure of the quality of alignment, was determined to be 0.63 ± 0.03 already for as-sedimented samples while the standard deviation of the orientation distribution of particles, another measure of average misalignment, was found to be (21.5 ± 1.4)°. After pressing, these values further improved to (0.81 ± 0.01) and (14.6 ± 0.4)°, respectively. Such quality of alignment competes with, if not even exceeds, values reported in the literature., Bioinspired materials, Characterization and analytical techniques, Design, synthesis and processing, Self-assembly |
swb_id_str | 9894427596 |
title | Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation |
title_auth | Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation |
title_full | Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation Sebastian Behr, Ulla Vainio, Martin Müller, Andreas Schreyer & Gerold A. Schneider |
title_fullStr | Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation Sebastian Behr, Ulla Vainio, Martin Müller, Andreas Schreyer & Gerold A. Schneider |
title_full_unstemmed | Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation Sebastian Behr, Ulla Vainio, Martin Müller, Andreas Schreyer & Gerold A. Schneider |
title_in_hierarchy | Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation / Sebastian Behr, Ulla Vainio, Martin Müller, Andreas Schreyer & Gerold A. Schneider, |
title_short | Large-scale parallel alignment of platelet-shaped particles through gravitational sedimentation |
title_sort | large scale parallel alignment of platelet shaped particles through gravitational sedimentation |
topic | Bioinspired materials, Characterization and analytical techniques, Design, synthesis and processing, Self-assembly |
topic_facet | Bioinspired materials, Characterization and analytical techniques, Design, synthesis and processing, Self-assembly |
url | https://doi.org/10.1038%2Fsrep09984, http://nbn-resolving.de/urn:nbn:de:gbv:830-88216427, https://doi.org/10.15480/882.1399, http://hdl.handle.net/11420/1402 |
urn | urn:nbn:de:gbv:830-88216427 |