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Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films
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| Veröffentlicht in: | Journal of solid state electrochemistry 24(2020), 11/12, Seite 3231-3244 |
|---|---|
| Personen und Körperschaften: | , , , |
| Titel: | Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films/ Violeta-Tincuţa Gruia, Adriana Ispas, Igor Efimov, Andreas Bund |
| Format: | E-Book-Kapitel |
| Sprache: | Englisch |
| veröffentlicht: |
2020
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| Gesamtaufnahme: |
: Journal of solid state electrochemistry, 24(2020), 11/12, Seite 3231-3244
, volume:24 |
| Quelle: | Verbunddaten SWB Lizenzfreie Online-Ressourcen |
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| 520 | |a Poly (3,4-ethylenedioxythiophene), PEDOT, films were synthesized at room temperature by potentiodynamic and potentiostatic step deposition in aqueous solutions containing EDOT monomer and LiClO4. In some solutions, the effect of small amounts of sodium dodecylsulfate, SDS, on the polymerization rate of EDOT and on the stiffness of the obtained PEDOT film was studied. The obtained PEDOT films were transferred in aqueous solutions containing cations with different molar mass, such as H+, Li+, Na+, K+, and Cs+. The apparent molar masses of the exchanged species during potentiodynamic experiments were determined by in situ microgravimetry. These measurements underlined the importance of the electrolyte chosen for electropolymerization process. It is known that SDS anions can be trapped inside the polymer layer during electropolymerization, providing them with a cation exchange behavior. However, even if the PEDOT films were deposited from an electrolyte without SDS, they still acted as cation exchangers. | ||
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| contents | Poly (3,4-ethylenedioxythiophene), PEDOT, films were synthesized at room temperature by potentiodynamic and potentiostatic step deposition in aqueous solutions containing EDOT monomer and LiClO4. In some solutions, the effect of small amounts of sodium dodecylsulfate, SDS, on the polymerization rate of EDOT and on the stiffness of the obtained PEDOT film was studied. The obtained PEDOT films were transferred in aqueous solutions containing cations with different molar mass, such as H+, Li+, Na+, K+, and Cs+. The apparent molar masses of the exchanged species during potentiodynamic experiments were determined by in situ microgravimetry. These measurements underlined the importance of the electrolyte chosen for electropolymerization process. It is known that SDS anions can be trapped inside the polymer layer during electropolymerization, providing them with a cation exchange behavior. However, even if the PEDOT films were deposited from an electrolyte without SDS, they still acted as cation exchangers. |
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| spelling | Gruia, Violeta-Tincuta 1976- VerfasserIn (DE-588)110810651X (DE-627)863725414 (DE-576)475348303 aut, Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films Violeta-Tincuţa Gruia, Adriana Ispas, Igor Efimov, Andreas Bund, 2020, Text txt rdacontent, Computermedien c rdamedia, Online-Ressource cr rdacarrier, DE-Ilm1 Open Access Controlled Vocabulary for Access Rights http://purl.org/coar/access_right/c_abf2, Poly (3,4-ethylenedioxythiophene), PEDOT, films were synthesized at room temperature by potentiodynamic and potentiostatic step deposition in aqueous solutions containing EDOT monomer and LiClO4. In some solutions, the effect of small amounts of sodium dodecylsulfate, SDS, on the polymerization rate of EDOT and on the stiffness of the obtained PEDOT film was studied. The obtained PEDOT films were transferred in aqueous solutions containing cations with different molar mass, such as H+, Li+, Na+, K+, and Cs+. The apparent molar masses of the exchanged species during potentiodynamic experiments were determined by in situ microgravimetry. These measurements underlined the importance of the electrolyte chosen for electropolymerization process. It is known that SDS anions can be trapped inside the polymer layer during electropolymerization, providing them with a cation exchange behavior. However, even if the PEDOT films were deposited from an electrolyte without SDS, they still acted as cation exchangers., DE-Ilm1 Namensnennung 4.0 International CC BY 4.0 cc https://creativecommons.org/licenses/by/4.0/, Ispas, Adriana 1977- VerfasserIn (DE-588)133699129 (DE-627)551112573 (DE-576)274488647 aut, Efimov, Igor VerfasserIn aut, Bund, Andreas 1969- VerfasserIn (DE-588)12967477X (DE-627)477115330 (DE-576)188639063 aut, Enthalten in Journal of solid state electrochemistry Berlin : Springer, 1997 24(2020), 11/12, Seite 3231-3244 Online-Ressource (DE-627)271175400 (DE-600)1478940-1 (DE-576)113948115 1433-0768 nnns, volume:24 year:2020 number:11/12 pages:3231-3244, https://doi.org/10.1007/s10008-020-04809-6 Verlag Resolving-System kostenfrei Volltext, https://www.db-thueringen.de/receive/dbt_mods_00047861 DE-601 Verlag kostenfrei Volltext, https://doi.org/10.1007/s10008-020-04809-6 LFER, LFER 2020-11-11T09:12:02Z |
| spellingShingle | Gruia, Violeta-Tincuta, Ispas, Adriana, Efimov, Igor, Bund, Andreas, Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films, Poly (3,4-ethylenedioxythiophene), PEDOT, films were synthesized at room temperature by potentiodynamic and potentiostatic step deposition in aqueous solutions containing EDOT monomer and LiClO4. In some solutions, the effect of small amounts of sodium dodecylsulfate, SDS, on the polymerization rate of EDOT and on the stiffness of the obtained PEDOT film was studied. The obtained PEDOT films were transferred in aqueous solutions containing cations with different molar mass, such as H+, Li+, Na+, K+, and Cs+. The apparent molar masses of the exchanged species during potentiodynamic experiments were determined by in situ microgravimetry. These measurements underlined the importance of the electrolyte chosen for electropolymerization process. It is known that SDS anions can be trapped inside the polymer layer during electropolymerization, providing them with a cation exchange behavior. However, even if the PEDOT films were deposited from an electrolyte without SDS, they still acted as cation exchangers. |
| title | Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films |
| title_auth | Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films |
| title_full | Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films Violeta-Tincuţa Gruia, Adriana Ispas, Igor Efimov, Andreas Bund |
| title_fullStr | Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films Violeta-Tincuţa Gruia, Adriana Ispas, Igor Efimov, Andreas Bund |
| title_full_unstemmed | Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films Violeta-Tincuţa Gruia, Adriana Ispas, Igor Efimov, Andreas Bund |
| title_in_hierarchy | Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films / Violeta-Tincuţa Gruia, Adriana Ispas, Igor Efimov, Andreas Bund, |
| title_short | Cation exchange behavior during the redox switching of poly (3,4-ethylenedioxythiophene) films |
| title_sort | cation exchange behavior during the redox switching of poly 3 4 ethylenedioxythiophene films |
| url | https://doi.org/10.1007/s10008-020-04809-6, https://www.db-thueringen.de/receive/dbt_mods_00047861 |