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Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid
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| Veröffentlicht in: | Energy reports 5(2019) vom: Nov., Seite 1463-1469 |
|---|---|
| Personen und Körperschaften: | , , , , , |
| Titel: | Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid/ Balaji Panchal, Shenjun Qin, Tao Chang, Yuzhuang Sun, Jinxi Wang, Kai Bian |
| Format: | E-Book-Kapitel |
| Sprache: | Englisch |
| veröffentlicht: |
2019
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| Gesamtaufnahme: |
: Energy reports, 5(2019) vom: Nov., Seite 1463-1469
, volume:5 |
| Schlagwörter: | |
| Quelle: | Verbunddaten SWB Lizenzfreie Online-Ressourcen |
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| 520 | |a Energy demand is increasing dramatically because of the fast industrial development, rising population, and economic growth in the world. To fulfill this energy demand, a large amount of fuel is widely used from different fossil resources. Burning of fossil fuels has caused serious detrimental environmental consequences. The application of methyl esters has shown a positive impact in resolving these issues. The objective of this study, methyl esters were produced by transesterification of fried soybean oil with dimethyl carbonate using hydrobromic acid as catalyst. Optimized several factors that affected the reaction efficiency including the fried soybean oil to dimethyl carbonate ratio (1:4 v/v), 3.5 % v/v catalyst concentration, a reaction temperature of 80 ºC for 50 min with 300 rpm agitation speed. The methyl esters yield was 94 % obtained using these optimized conditions. Methyl esters were purified by ion exchange resin amberlite-732, and purified methyl esters were analyzed by GC-MS. We then characterized important physical properties of methyl esters such as kinematic viscosity, density, flash point, cloud point, and pour point. These properties were found to have met with the quality standard defined under ASTM D6751-02 and compared with diesel fuel. In this research, a novel method was developed for the production of methyl esters under mild conditions using dimethyl carbonate and hydrobromic acid. | ||
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| contents | Energy demand is increasing dramatically because of the fast industrial development, rising population, and economic growth in the world. To fulfill this energy demand, a large amount of fuel is widely used from different fossil resources. Burning of fossil fuels has caused serious detrimental environmental consequences. The application of methyl esters has shown a positive impact in resolving these issues. The objective of this study, methyl esters were produced by transesterification of fried soybean oil with dimethyl carbonate using hydrobromic acid as catalyst. Optimized several factors that affected the reaction efficiency including the fried soybean oil to dimethyl carbonate ratio (1:4 v/v), 3.5 % v/v catalyst concentration, a reaction temperature of 80 ºC for 50 min with 300 rpm agitation speed. The methyl esters yield was 94 % obtained using these optimized conditions. Methyl esters were purified by ion exchange resin amberlite-732, and purified methyl esters were analyzed by GC-MS. We then characterized important physical properties of methyl esters such as kinematic viscosity, density, flash point, cloud point, and pour point. These properties were found to have met with the quality standard defined under ASTM D6751-02 and compared with diesel fuel. In this research, a novel method was developed for the production of methyl esters under mild conditions using dimethyl carbonate and hydrobromic acid. |
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| spelling | Panchal, Balaji VerfasserIn (DE-588)1200661621 (DE-627)168381746X aut, Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid Balaji Panchal, Shenjun Qin, Tao Chang, Yuzhuang Sun, Jinxi Wang, Kai Bian, 2019, Text txt rdacontent, Computermedien c rdamedia, Online-Ressource cr rdacarrier, Energy demand is increasing dramatically because of the fast industrial development, rising population, and economic growth in the world. To fulfill this energy demand, a large amount of fuel is widely used from different fossil resources. Burning of fossil fuels has caused serious detrimental environmental consequences. The application of methyl esters has shown a positive impact in resolving these issues. The objective of this study, methyl esters were produced by transesterification of fried soybean oil with dimethyl carbonate using hydrobromic acid as catalyst. Optimized several factors that affected the reaction efficiency including the fried soybean oil to dimethyl carbonate ratio (1:4 v/v), 3.5 % v/v catalyst concentration, a reaction temperature of 80 ºC for 50 min with 300 rpm agitation speed. The methyl esters yield was 94 % obtained using these optimized conditions. Methyl esters were purified by ion exchange resin amberlite-732, and purified methyl esters were analyzed by GC-MS. We then characterized important physical properties of methyl esters such as kinematic viscosity, density, flash point, cloud point, and pour point. These properties were found to have met with the quality standard defined under ASTM D6751-02 and compared with diesel fuel. In this research, a novel method was developed for the production of methyl esters under mild conditions using dimethyl carbonate and hydrobromic acid., Aufsatz in Zeitschrift DE-206, Qin, Shenjun VerfasserIn (DE-588)1200661710 (DE-627)1683817788 aut, Chang, Tao VerfasserIn (DE-588)1200661788 (DE-627)1683817885 aut, Sun, Yuzhuang VerfasserIn (DE-588)1200661869 (DE-627)1683818059 aut, Wang, Jinxiang VerfasserIn (DE-588)1214248012 (DE-627)1725192764 aut, Bian, Kai VerfasserIn (DE-588)1200662075 (DE-627)1683818369 aut, Enthalten in Energy reports Amsterdam [u.a.] : Elsevier, 2015 5(2019) vom: Nov., Seite 1463-1469 Online-Ressource (DE-627)820689033 (DE-600)2814795-9 (DE-576)427950821 2352-4847 nnns, volume:5 year:2019 month:11 pages:1463-1469, https://doi.org/10.1016/j.egyr.2019.10.007 Resolving-System kostenfrei, https://www.sciencedirect.com/science/article/pii/S2352484719302707/pdfft?md5=1c67ffa7311ea3bb176d0706acd37ac7&pid=1-s2.0-S2352484719302707-main.pdf Verlag kostenfrei, http://hdl.handle.net/10419/243686 Resolving-System kostenfrei, https://creativecommons.org/licenses/by-nc-nd/4.0/ Verlag Terms of use, https://doi.org/10.1016/j.egyr.2019.10.007 LFER, https://www.sciencedirect.com/science/article/pii/S2352484719302707/pdfft?md5=1c67ffa7311ea3bb176d0706acd37ac7&pid=1-s2.0-S2352484719302707-main.pdf LFER, LFER 2020-02-17T00:00:00Z |
| spellingShingle | Panchal, Balaji, Qin, Shenjun, Chang, Tao, Sun, Yuzhuang, Wang, Jinxiang, Bian, Kai, Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid, Energy demand is increasing dramatically because of the fast industrial development, rising population, and economic growth in the world. To fulfill this energy demand, a large amount of fuel is widely used from different fossil resources. Burning of fossil fuels has caused serious detrimental environmental consequences. The application of methyl esters has shown a positive impact in resolving these issues. The objective of this study, methyl esters were produced by transesterification of fried soybean oil with dimethyl carbonate using hydrobromic acid as catalyst. Optimized several factors that affected the reaction efficiency including the fried soybean oil to dimethyl carbonate ratio (1:4 v/v), 3.5 % v/v catalyst concentration, a reaction temperature of 80 ºC for 50 min with 300 rpm agitation speed. The methyl esters yield was 94 % obtained using these optimized conditions. Methyl esters were purified by ion exchange resin amberlite-732, and purified methyl esters were analyzed by GC-MS. We then characterized important physical properties of methyl esters such as kinematic viscosity, density, flash point, cloud point, and pour point. These properties were found to have met with the quality standard defined under ASTM D6751-02 and compared with diesel fuel. In this research, a novel method was developed for the production of methyl esters under mild conditions using dimethyl carbonate and hydrobromic acid., Aufsatz in Zeitschrift |
| title | Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid |
| title_auth | Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid |
| title_full | Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid Balaji Panchal, Shenjun Qin, Tao Chang, Yuzhuang Sun, Jinxi Wang, Kai Bian |
| title_fullStr | Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid Balaji Panchal, Shenjun Qin, Tao Chang, Yuzhuang Sun, Jinxi Wang, Kai Bian |
| title_full_unstemmed | Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid Balaji Panchal, Shenjun Qin, Tao Chang, Yuzhuang Sun, Jinxi Wang, Kai Bian |
| title_in_hierarchy | Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid / Balaji Panchal, Shenjun Qin, Tao Chang, Yuzhuang Sun, Jinxi Wang, Kai Bian, |
| title_short | Production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid |
| title_sort | production of methyl esters from fried soybean oil using dimethyl carbonate with hydrobromic acid |
| topic | Aufsatz in Zeitschrift |
| topic_facet | Aufsatz in Zeitschrift |
| url | https://doi.org/10.1016/j.egyr.2019.10.007, https://www.sciencedirect.com/science/article/pii/S2352484719302707/pdfft?md5=1c67ffa7311ea3bb176d0706acd37ac7&pid=1-s2.0-S2352484719302707-main.pdf, http://hdl.handle.net/10419/243686, https://creativecommons.org/licenses/by-nc-nd/4.0/ |