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Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis
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| Zeitschriftentitel: | Laser Chemistry |
|---|---|
| Personen und Körperschaften: | , , |
| In: | Laser Chemistry, 3, 1983, 1-6, S. 97-106 |
| Format: | E-Article |
| Sprache: | Englisch |
| veröffentlicht: |
Hindawi Limited
|
| Schlagwörter: |
| author_facet |
Lahmani, F. Lardeux, C. Solgadi, D. Lahmani, F. Lardeux, C. Solgadi, D. |
|---|---|
| author |
Lahmani, F. Lardeux, C. Solgadi, D. |
| spellingShingle |
Lahmani, F. Lardeux, C. Solgadi, D. Laser Chemistry Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis Spectroscopy Biochemistry Atomic and Molecular Physics, and Optics |
| author_sort |
lahmani, f. |
| spelling |
Lahmani, F. Lardeux, C. Solgadi, D. 0278-6273 1476-3516 Hindawi Limited Spectroscopy Biochemistry Atomic and Molecular Physics, and Optics http://dx.doi.org/10.1155/lc.3.97 <jats:p>The photodissociation of methyl nitrite CH<jats:sub>3</jats:sub>ONO in three different electronically excited states has been studied by determining the internal state distribution of one of the photofragments. The fluorescence of NO A<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo><mml:mmultiscripts><mml:mi>Σ</mml:mi><mml:mprescripts /><mml:none /><mml:mn>2</mml:mn></mml:mmultiscripts></mml:math><jats:sup>+</jats:sup> produced for excitation of CH<jats:sub>3</jats:sub>ONO between 1200 and 1650 Å and of CH<jats:sub>3</jats:sub>O <jats:sup>2</jats:sup><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo></mml:math>A<jats:sub>1</jats:sub> produced at 1930 Å has been investigated. The vibrational distribution in both species can be explained by statistical considerations. The rotational excitation of NO A<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo><mml:mmultiscripts><mml:mi>Σ</mml:mi><mml:mprescripts /><mml:none /><mml:mn>2</mml:mn></mml:mmultiscripts></mml:math><jats:sup>+</jats:sup> is of Boltzmann type. For CH<jats:sub>3</jats:sub>ONO excited in the first nπ* excited state at 3550 Å the NO X fragment has been probed by a two photon laser excited fluorescence technique. The nascent NO X υ″ = 0, 1, 2, 3 exhibit a population inversion and a high degree of rotational excitation.</jats:p> Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis Laser Chemistry |
| doi_str_mv |
10.1155/lc.3.97 |
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Online Free |
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Chemie und Pharmazie Physik |
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ElectronicArticle |
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DE-Ch1 DE-L229 DE-D275 DE-Bn3 DE-Brt1 DE-Zwi2 DE-D161 DE-Gla1 DE-Zi4 DE-15 DE-Pl11 DE-Rs1 DE-105 DE-14 |
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Hindawi Limited, 1983 |
| imprint_str_mv |
Hindawi Limited, 1983 |
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0278-6273 1476-3516 |
| issn_str_mv |
0278-6273 1476-3516 |
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English |
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Hindawi Limited (CrossRef) |
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lahmani1983energypartitioninginmolecularphotodissociationmethylnitritephotolysis |
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1983 |
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Hindawi Limited |
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ai |
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ai |
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Laser Chemistry |
| source_id |
49 |
| title |
Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_unstemmed |
Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_full |
Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_fullStr |
Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_full_unstemmed |
Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_short |
Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_sort |
energy partitioning in molecular photodissociation: methyl nitrite photolysis |
| topic |
Spectroscopy Biochemistry Atomic and Molecular Physics, and Optics |
| url |
http://dx.doi.org/10.1155/lc.3.97 |
| publishDate |
1983 |
| physical |
97-106 |
| description |
<jats:p>The photodissociation of methyl nitrite CH<jats:sub>3</jats:sub>ONO in three different electronically
excited states has been studied by determining the internal state distribution of one
of the photofragments. The fluorescence of NO A<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo><mml:mmultiscripts><mml:mi>Σ</mml:mi><mml:mprescripts /><mml:none /><mml:mn>2</mml:mn></mml:mmultiscripts></mml:math><jats:sup>+</jats:sup> produced for excitation of
CH<jats:sub>3</jats:sub>ONO between 1200 and 1650 Å and of CH<jats:sub>3</jats:sub>O <jats:sup>2</jats:sup><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo></mml:math>A<jats:sub>1</jats:sub> produced at 1930 Å has been
investigated. The vibrational distribution in both species can be explained by statistical
considerations. The rotational excitation of NO A<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo><mml:mmultiscripts><mml:mi>Σ</mml:mi><mml:mprescripts /><mml:none /><mml:mn>2</mml:mn></mml:mmultiscripts></mml:math><jats:sup>+</jats:sup> is of Boltzmann type. For
CH<jats:sub>3</jats:sub>ONO excited in the first nπ* excited state at 3550 Å the NO X fragment has
been probed by a two photon laser excited fluorescence technique. The nascent
NO X υ″ = 0, 1, 2, 3 exhibit a population inversion and a high degree of rotational
excitation.</jats:p> |
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| author | Lahmani, F., Lardeux, C., Solgadi, D. |
| author_facet | Lahmani, F., Lardeux, C., Solgadi, D., Lahmani, F., Lardeux, C., Solgadi, D. |
| author_sort | lahmani, f. |
| container_issue | 1-6 |
| container_start_page | 97 |
| container_title | Laser Chemistry |
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| description | <jats:p>The photodissociation of methyl nitrite CH<jats:sub>3</jats:sub>ONO in three different electronically excited states has been studied by determining the internal state distribution of one of the photofragments. The fluorescence of NO A<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo><mml:mmultiscripts><mml:mi>Σ</mml:mi><mml:mprescripts /><mml:none /><mml:mn>2</mml:mn></mml:mmultiscripts></mml:math><jats:sup>+</jats:sup> produced for excitation of CH<jats:sub>3</jats:sub>ONO between 1200 and 1650 Å and of CH<jats:sub>3</jats:sub>O <jats:sup>2</jats:sup><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo></mml:math>A<jats:sub>1</jats:sub> produced at 1930 Å has been investigated. The vibrational distribution in both species can be explained by statistical considerations. The rotational excitation of NO A<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo><mml:mmultiscripts><mml:mi>Σ</mml:mi><mml:mprescripts /><mml:none /><mml:mn>2</mml:mn></mml:mmultiscripts></mml:math><jats:sup>+</jats:sup> is of Boltzmann type. For CH<jats:sub>3</jats:sub>ONO excited in the first nπ* excited state at 3550 Å the NO X fragment has been probed by a two photon laser excited fluorescence technique. The nascent NO X υ″ = 0, 1, 2, 3 exhibit a population inversion and a high degree of rotational excitation.</jats:p> |
| doi_str_mv | 10.1155/lc.3.97 |
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| id | ai-49-aHR0cDovL2R4LmRvaS5vcmcvMTAuMTE1NS9sYy4zLjk3 |
| imprint | Hindawi Limited, 1983 |
| imprint_str_mv | Hindawi Limited, 1983 |
| institution | DE-Ch1, DE-L229, DE-D275, DE-Bn3, DE-Brt1, DE-Zwi2, DE-D161, DE-Gla1, DE-Zi4, DE-15, DE-Pl11, DE-Rs1, DE-105, DE-14 |
| issn | 0278-6273, 1476-3516 |
| issn_str_mv | 0278-6273, 1476-3516 |
| language | English |
| last_indexed | 2024-03-01T17:50:49.51Z |
| match_str | lahmani1983energypartitioninginmolecularphotodissociationmethylnitritephotolysis |
| mega_collection | Hindawi Limited (CrossRef) |
| physical | 97-106 |
| publishDate | 1983 |
| publishDateSort | 1983 |
| publisher | Hindawi Limited |
| record_format | ai |
| recordtype | ai |
| series | Laser Chemistry |
| source_id | 49 |
| spelling | Lahmani, F. Lardeux, C. Solgadi, D. 0278-6273 1476-3516 Hindawi Limited Spectroscopy Biochemistry Atomic and Molecular Physics, and Optics http://dx.doi.org/10.1155/lc.3.97 <jats:p>The photodissociation of methyl nitrite CH<jats:sub>3</jats:sub>ONO in three different electronically excited states has been studied by determining the internal state distribution of one of the photofragments. The fluorescence of NO A<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo><mml:mmultiscripts><mml:mi>Σ</mml:mi><mml:mprescripts /><mml:none /><mml:mn>2</mml:mn></mml:mmultiscripts></mml:math><jats:sup>+</jats:sup> produced for excitation of CH<jats:sub>3</jats:sub>ONO between 1200 and 1650 Å and of CH<jats:sub>3</jats:sub>O <jats:sup>2</jats:sup><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo></mml:math>A<jats:sub>1</jats:sub> produced at 1930 Å has been investigated. The vibrational distribution in both species can be explained by statistical considerations. The rotational excitation of NO A<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo> </mml:mo><mml:mmultiscripts><mml:mi>Σ</mml:mi><mml:mprescripts /><mml:none /><mml:mn>2</mml:mn></mml:mmultiscripts></mml:math><jats:sup>+</jats:sup> is of Boltzmann type. For CH<jats:sub>3</jats:sub>ONO excited in the first nπ* excited state at 3550 Å the NO X fragment has been probed by a two photon laser excited fluorescence technique. The nascent NO X υ″ = 0, 1, 2, 3 exhibit a population inversion and a high degree of rotational excitation.</jats:p> Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis Laser Chemistry |
| spellingShingle | Lahmani, F., Lardeux, C., Solgadi, D., Laser Chemistry, Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis, Spectroscopy, Biochemistry, Atomic and Molecular Physics, and Optics |
| title | Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_full | Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_fullStr | Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_full_unstemmed | Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_short | Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| title_sort | energy partitioning in molecular photodissociation: methyl nitrite photolysis |
| title_unstemmed | Energy Partitioning in Molecular Photodissociation: Methyl Nitrite Photolysis |
| topic | Spectroscopy, Biochemistry, Atomic and Molecular Physics, and Optics |
| url | http://dx.doi.org/10.1155/lc.3.97 |